industrial waste

A green battery from industrial waste

February 11, 2025 By EarthWise Leave a Comment

Flow batteries are rechargeable batteries in which liquid electrolytes flow through one or more chemical cells from one or more tanks. The electrolytes are redox pairs, that is, chemical compounds that can reversibly undergo reduction and oxidation reactions. The most common redox electrolytes include elements like vanadium, chromium, iron, zinc, and bromine. Flow batteries can provide large amounts of both electrical power and stored energy based on the size of the electrolyte tanks. As a result, they can be scaled up far more readily than other battery technologies.

Flow batteries are safe, stable, long-lasting, and their electrolytes can easily be refilled. They have significant potential for use in utility-scale storage for renewable energy systems.

Researchers at Northwestern University have developed a redox flow battery based on an organic industrial-scale waste product. The material – triphenylphosphine oxide or TPPO – is produced in the thousands of tons each year. It is byproduct of producing a variety of substances including some vitamins, pharmaceuticals, agrochemicals, and other bulk chemicals. For the most part, TPPO is of little use and must be carefully discarded.

The current market for redox flow batteries is very small but is expected to grow over time as the need for utility-scale energy storage continues to expand. A battery technology based on a waste material that is already produced in high volume and that must otherwise be disposed of with caution would have significant advantages.

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Green battery discovery turns trash into treasure

Photo, posted January 12, 2015, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Getting Rid Of Hydrogen Sulfide | Earth Wise

December 20, 2022 By EarthWise Leave a Comment

Hydrogen sulfide gas produces the characteristic smell of rotten eggs, sewers, stockyards, and landfills. The petroleum industry produces thousands of tons of the stuff each year as a byproduct of the processes that remove sulfur from petroleum, natural gas, coal, and other products. The industry faces substantial fines for emitting hydrogen sulfide, but remediation is expensive.

Researchers at Rice University have developed a method for turning hydrogen sulfide into hydrogen gas and sulfur in a single step. Called plasmonic photocatalysis, it not only gets rid of an undesirable substance, it does so by producing valuable byproducts.

The established way of getting rid of hydrogen sulfide is called the Claus process. It requires multiple steps, including some that require combustion chambers heated to 1,500 degrees Fahrenheit. The end product is sulfur and water.

The Rice University process gets all of its energy from light. A surface of grains of silicon dioxide is dotted with tiny gold nanoparticles. These particles interact strongly with a specific wavelength of visible light and cause plasmonic reactions that create short-lived, high-energy electrons that drive the catalysis of hydrogen sulfide. Given that the process requires only visible light and no external heating, it should be relatively straightforward to scale up using solar energy or very efficient LED lamps.

The new hydrogen sulfide remediation technology has been licensed by a Houston-based startup company with more than 60 employees whose founders include some of the Rice researchers. The process may end up being efficient enough and cheap enough for cleaning up non-industrial sources of hydrogen sulfide such as sewers and animal waste.

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New catalyst can turn smelly hydrogen sulfide into a cash cow

Photo, posted July 8, 2021, courtesy of Doug Letterman via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Whales In The Big Apple

July 12, 2017 By EarthWise

For the first time in a century, humpback whales have returned to the waters of New York harbor. These are not rare sightings, either. The whales are showing up in enough numbers that a company is taking tourists out into the harbor to see whales with a backdrop of Manhattan skyscrapers.

Coal Plants And Fish

March 20, 2017 By EarthWise

High levels of an element found in coal ash have been detected in fish in two lakes where Duke Energy coal-fired power plants are located, according to a peer-reviewed study at Duke University. The element, selenium, occurs naturally but is concentrated in coal ash.

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Microplastics And Salt

December 10, 2015 By WAMC WEB

Today, thousands of personal care products – such as facial scrubs, body washes, and toothpastes – are known to contain minuscule balls of plastic called microbeads. When we shower or brush our teeth, these microbeads are washed down the drain and travel undetected through wastewater treatment plants. When they reach their final destination — our lakes, rivers and oceans — they mix with other sources of microplastics, including industrial waste and degraded plastic litter.