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Sustainable hydrogen from methane

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Hydrogen could serve as a viable alternative to fossil fuels that can be used directly as a fuel or can be used to generate electricity to power cars and other devices. However, large-scale production of hydrogen currently relies on fossil fuels and creates carbon emissions in the process.

So-called green hydrogen involves using electricity to split water into its component elements to produce it.  If the electricity is generated without emissions, then the hydrogen is truly green.

Another way to get hydrogen is by breaking down hydrocarbons like methane, which itself is a very powerful greenhouse gas.  This so-called blue hydrogen could be environmentally friendly if an appropriate method for producing it can be developed.

Existing techniques for converting methane into hydrogen involve the use of metal catalysts – often nickel – that are energy-intensive to mine and manufacture, and can negatively affect the environment.  Research at the University of Surrey in the UK has shown promising results for the use of nitrogen-doped nanocarbons as metal-free catalysts for the direct conversion of methane into hydrogen.  One of the biggest problems with using metal catalysts for hydrogen production is that they get poisoned by carbon.  The carbon that comes out of the methane ends up stopping the catalyst from continuing to do its chemical job.  It turns out that the doped nanocarbon approach to hydrogen catalysis appears to be resistant to this problem.

The development of sustainable hydrogen production methods, including efficient and sustainable electrolysis of water as well as catalysis of hydrocarbons like methane, is crucial to realizing the potential of hydrogen fuel as a clean energy source.

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‘Game-changing’ findings for sustainable hydrogen production

Photo, posted April 30, 2021, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cleaning Up Diesel With Bacteria | Earth Wise

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Mothballed military outposts with piles of rusting oil drums are not an unusual sight in Greenland.  There are about 30 abandoned military installations in Greenland and diesel that was once used to operate generators and other machinery has, in many cases, seeped into the ground.

Removing tons of contaminated soil from these sites is incredibly resource-intensive involving the use of aircraft and ships, so it has not really been practical.  As a result, Danish Defense and the engineering company NIRAS instead conducted a five-year experiment to optimize the conditions for naturally occurring soil bacteria to break down the contaminating diesel.

The experiment was performed at Station 9117 Mestersvig, an abandoned military airfield on the coast of East Greenland.  Forty tons of diesel fuel contaminated the soil there.

The remediation method using bacteria is known as landfarming and has most often been applied in warmer climates around the world.  This was the first large-scale test under Arctic conditions.

Landfarming works by distributing contaminated soil in a thin layer, which is then plowed, fertilized, and oxygenated every year to optimize conditions for bacteria to degrade hydrocarbons.

The site was monitored by scientists from the University of Copenhagen, and they found that after five years, the bacteria had bioremediated as much as 82 percent of the 5,000 tons of contaminated soil on the site. 

Based on these results, it appears to be feasible for naturally occurring bacteria to be used to remediate contamination in all of the 30 deserted military installations in Greenland as well as in other Arctic sites contaminated by diesel pollution.

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Bacteria used to clean diesel-polluted soil in Greenland

Photo, posted September 6, 2013, courtesy of Maj. Matthew J. Sala/The U.S. Air National Guard via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The U.S. Military And Climate Change

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According to new research by scientists from Durham University and Lancaster University, the United States military is one of the largest climate polluters.  The U.S. military consumes more liquid fuels and emits more greenhouse gases than most countries.  

The study, published in Transactions of the Institute of British Geographers, finds that if the U.S. military were a country, it would be the 47th largest emitter of greenhouse gases in the world, falling between Peru and Portugal.  And this only takes into account the emissions from its liquid fuel consumption.  For this study, the U.S. military’s 2015 consumption was compared with the 2014 World Bank country liquid fuel consumption. 

In 2017, the U.S. military purchased more than 269,000 barrels of oil a day, emitting more than 25,000 kt- CO2e by burning those fuels.  The Air Force accounted for $4.9 billion worth of this fuel, followed by the Navy at $2.8 billion, the Army at $947 million, and the Marines at $36 million. 

The Air Force and the Navy are not only the U.S. military’s largest purchasers of fuel, they also use the most polluting types of fuel.  The Air Force is the largest emitter of greenhouse gases at more than 13,000 kt CO2e, nearly double that of the Navy’s 7,800 kt CO2e. 

Despite this study’s findings and a general uptick in awareness, it’s unlikely that the U.S. military’s dependence on fossil fuels will change.  That’s because the military continues to pursue open-ended operations around the globe, and the lifecycle of its existing military equipment insures dependence on hydrocarbons for many years to come. 

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U.S. military consumes more hydrocarbons than most countries — massive hidden impact on climate

Photo, posted July 8, 2016, courtesy of Alan Wilson via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Rigs To Reefs

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There are about 6,000 offshore oil platforms in the world’s oceans.  They have an immense presence physically, financially and environmentally.  As these massive structures extract hydrocarbons from deep beneath the sea, they also undergo a remarkable transformation under the water.  The enormous substructures that support the platforms become vertical reefs, home to millions of individual plants and animals.

Over time, many oil platforms are decommissioned, and their owners are faced with the choice of either removing them entirely or transitioning them into permanent reefs.   Traditional practice was to restore the site to its original condition, but more recently the idea of “reefing” old platforms has gained popularity.  As of 2016, more than 11% of decommissioned platforms in the U.S. portion of the Gulf of Mexico have become permanent reefs.

Decommissioning and completely removing a platform is a daunting and pricey proposition.  The most recent estimate for removing all platforms off the coast of California alone totals $8 billion.  Modifying the platforms to serve as permanent reefs cuts these costs significantly, especially those associated with hauling, cleaning and disposing of the underwater support structure, which will have thousands of tons of sea-life clinging to it by the time it is removed.

Converting the structure into a permanent reef means making it free of any hydrocarbons or other hazardous materials. But this is still a far cheaper venture than total removal.  Studies of oil rigs as underwater habitats have shown them to be some of the most productive in the world.  They are 3-dimensional reefs whose open construction allows currents to pass through bringing lots of nutrients.

Over time, more and more oil platforms will be decommissioned. Many may end up remaining as permanent homes for undersea life.

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Rigs to Reefs

Photo, posted August 21, 2011, courtesy of Marianne Muegenburg via Flickr

Earth Wise is a production of WAMC Northeast Public Radio.

Fossil Fuel Companies And Renewables

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There is a tendency to think of the changes in the energy industry as a pitched battle between fossil fuel companies and renewable energy.  There is some truth to this, but only to a certain extent.   The multi-trillion-dollar fossil fuel industry is made up of businesses dedicated to growth and increased profits.  And like businesses in other industries when major changes occur, fossil fuel companies may read the tea leaves and change with the times.

[Read more…] about Fossil Fuel Companies And Renewables

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