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Electricity from chicken feathers

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The food industry generates enormous amounts of waste and by-products.  Each year, 40 million tons of chicken feathers are incinerated, causing adverse environmental effects.  Not only does it release large amounts of carbon dioxide but also produces toxic gases such as sulfur dioxide.

Researchers at ETH Zurich in Switzerland and Nanyang Technological University in Singapore have developed a way to put chicken feathers to good use by using them to make fuel cells more cost-effective and sustainable.

Using a simple and environmentally friendly process, they extract the keratin from the feathers.  Keratin is the protein that helps form hair, nails, the outer layer of skin, and feathers.  The extracted keratin is then converted into ultra-fine fibers known as amyloid fibrils.  The keratin fibrils are used in the membrane of a fuel cell.

Fuel cells generate clean energy from hydrogen and oxygen with only heat and water as byproducts.  At the heart of every fuel cell is a semipermeable membrane that allows protons to pass through but blocks electrons, thereby producing an electric current.  Fuel cells are the primary way hydrogen is used to directly generate electricity.  Hydrogen cars run on fuel cells.

Conventional fuel cells typically use membranes made from highly toxic chemicals.  The new ETH membranes essentially replace these toxic substances with biological keratin. 

The researchers are investigating how stable and durable their keratin membrane is and to improve it if necessary.  The team has already applied for a joint patent and is looking for partners and investors to further develop the technology and bring it to market.

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Generating clean electricity with chicken feathers

Photo, posted July 10, 2016, courtesy of Matthew Bellemare via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Moisture swing carbon capture

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As the world grapples with limiting the amount of carbon dioxide in the atmosphere, there is a growing need to capture the carbon dioxide that is emitted as well as preventing it from being emitted in the first place.  Carbon capture can be accomplished at the source of emissions (such as power plants) or it can be done by taking it out of the atmosphere.  The latter is called “direct air capture”.

It is not at all clear whether direct air capture can be accomplished on a scale that would really make a difference and at an acceptable cost either in dollars or energy expended.  But if it can be done that way, it would be a major tool in combatting climate change.

Direct air capture technology generally makes use of sorbent materials whose capacity to capture carbon dioxide and later release it is a function of temperature.  The process requires significant amounts of energy to release the carbon dioxide that has been captured. 

New research from Northwestern University makes use of the “moisture-swing” technique which uses materials whose ability to capture and release carbon dioxide depends on humidity rather than temperature.  While it takes some amount of energy to humidify the volume of air containing the sorbent material, it is very small compared to temperature-driven systems. 

There are many groups working with moisture-swing technology, but the Northwestern Group has identified a number of new sorbent materials with superior properties.

The fundamental questions of scalability and cost remain, but moisture-swing is a promising approach to direct air capture.  If carbon dioxide can be pulled out of the atmosphere in large volumes, it can be concentrated and stored or converted into useful products.

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Pulling carbon dioxide right out of the air

Photo, posted May 15, 2020, courtesy of James Watt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Planting Rocks To Capture Carbon | Earth Wise

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Getting humanity to stop dumping carbon dioxide into the atmosphere continues to be very challenging regardless of how increasingly apparent the need to do so becomes.  For this reason, climate change mitigation strategies increasingly include interventions in the form of removing carbon dioxide that is already there.  There are a variety of ways to draw carbon dioxide out of the atmosphere, but they face a host of technological, economic, and even environmental difficulties.

A new study at Yale University evaluated a type of climate intervention called enhanced rock weathering.  Rock weathering is a natural chemical process by which certain minerals absorb carbon dioxide over time.  Enhanced rock weathering is simply speeding up weathering such so it can have beneficial results soon enough to make a difference.

The study explored the potential of applying crushed basalt, which is a fast-weathering rock that forms when lava cools, to agricultural fields around the world.  Basically, the idea is for farmers to mix the crushed rocks into their fields. There is no real downside to doing this.  In fact, adding crushed basalt to fields rejuvenates depleted soils and helps counter ocean acidification.

The study simulated the results of enhanced rock weathering on 1,000 agricultural sites around the world.  Over a 75-year period, these sites would remove 64 billion tons of carbon dioxide from the atmosphere.  This is roughly the amount climate scientists believe is needed to take out of the atmosphere. 

Enhanced rock weathering has been used on a small scale on farms around the world.  Perhaps it is time to ramp up its use.

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‘Planting’ rocks in farms, along with emissions reductions, could help meet key IPCC carbon removal goal

Photo, posted January 14, 2023, courtesy of Ron Reiring via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Protecting The Amazon Rainforest | Earth Wise

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The Amazon rainforest absorbs one-fourth of all the carbon dioxide absorbed by the land of the Earth.  It is by far the world’s largest rainforest, bigger than the next two largest – in the Congo Basin and Indonesia – combined.  Nearly two-thirds of it is found in Brazil but the more than 2 million square miles of rainforest includes portions in 8 countries.

The amount of carbon dioxide absorbed by the Amazon rainforest is 30% less today than it was in the 1990s as a result of deforestation, to a great extent driven by cattle ranching as well as other agricultural activities.

In early August, the leaders of the eight countries that are home to the Amazon River basin agreed to work together to conserve the rainforest.  The agreement, called the Belém Declaration, provides a roadmap to stave off the rampant deforestation. 

The agreement provides coordination between the countries of Bolivia, Brazil, Colombia, Ecuador, Guyana, Peru, Suriname, and Venezuela to establish law enforcement to combat illegal mining and logging as well as to pool development funds for conservation and sustainable employment.  Despite the unity portrayed at the meeting, many of the governments in South America are in a precarious position because of various economic and political struggles

Apart from its critical climate impact, the Amazon rainforest is a haven for biodiversity and further deforestation would be disastrous for tens of thousands of species and could transform it into a net emitter rather than absorber of greenhouse gases.  Some parts of the region have already reached that point.

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Amazon Countries, Led by Brazil, Sign a Rainforest Pact

Photo, posted October 17, 2016, courtesy of Yeoboya via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Endangered Plants And The Changing Climate | Earth Wise

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Plants are a critical resource because of the countless ways they support life on Earth. Plants release oxygen into the atmosphere, absorb carbon dioxide, and provide food and habitat for humans and wildlife.  Plants are also used to produce fibers, building materials, and medicines. 

Plants form the backbone of natural ecosystems, and absorb about 30% of all the carbon dioxide emitted by humans each year.  But plants are struggling to adapt in a human-dominated world.  Even though they are easier and cheaper to protect than animals, plants are often overlooked in conservation efforts.

Ironically, conservation efforts appear to be overlooking a key threat to endangered plants.  According to a new study led by researchers from Penn State University, all plants and lichens listed as endangered under the Endangered Species Act are sensitive to climate change, but there are few plans in place to address that threat directly. 

The threat that climate change poses to endangered plants and lichens had not been thoroughly evaluated in more than a decade.  In the study, which was recently published in the journal PLOS Climate, the research team adapted existing assessment tools used to examine the threat of climate change for wild animals and applied them to 771 endangered plant species.  The researchers found that all endangered plant and lichen species are at least slightly threatened by climate change, and little is being done to protect the listed species from that threat.

The researchers hope their findings will be used to aid future conservation planning.  After all, plants can live without humans, but humans cannot live without plants.

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Climate change threatens 771 endangered plant and lichen species

Photo, posted June 12, 2014, courtesy of Mark Freeth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Methane Emissions And The Paris Agreement | Earth Wise

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The Paris Agreement is a legally binding international treaty on climate change adopted at the UN Climate Change Conference in 2015.  Its goal is to strengthen the global response to climate change by committing to limit the rise in global average temperature to well below 2°C above pre-industrial levels, and pursue efforts to limit that increase to just 1.5°C. 

Achieving the goals of the Paris Agreement requires reaching net-zero carbon dioxide emissions by or around 2050, as well as deep reductions in methane and other emissions. 

According to a new study by researchers from Simon Fraser University in Canada, reductions in methane emissions are needed urgently  if we are to meet the goals of the Paris Agreement.  The study, which was recently published in the journal Nature’s Communications Earth & Environment, suggests that global warming levels could be kept below 2°C if methane mitigation efforts are initiated globally before 2030.  However, delaying methane mitigation to the year 2040 or beyond would increase the risk of exceeding 2°C, even if net-zero carbon dioxide emissions were achieved.

Methane is a potent greenhouse gas, second only to carbon dioxide in contributing to global temperature increases over the last two centuries.  However, methane is known to warm the planet 86 times more effectively than carbon dioxide over a 20-year period.

During the past 40 years, more than 60% of global methane emissions have been produced as a result of human activities, such as fossil fuel exploitation, livestock production, and waste from landfills.

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Delaying methane mitigation increases risk of breaching Paris Agreement climate goal, study finds

Photo, posted July 22, 2011, courtesy of Steven W. via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cleaner And Greener Steel | Earth Wise

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Producing construction materials like concrete and steel is a major contributor to greenhouse gas emissions.  Between 7 and 8% of emissions are due to steelmaking alone, which has been done pretty much the same way for more than a century.

Iron ore is smelted with high-carbon fuel and is turned into so-called pig iron in a blast furnace, which creates the key raw material for the steel industry.  The process uses huge amounts of energy (still often generated by burning fossil fuels) and releases carbon dioxide as a byproduct. 

The Department of Energy is sponsoring 40 projects at universities, national laboratories and companies in 21 states aimed at reducing industrial carbon pollution.  Ten of those projects are focused on decarbonizing iron and steel. These initiatives are part of the overall effort to move the nation towards a net-zero emissions economy by 2050.

A team headed by Case Western Reserve University that includes Lawrence Livermore National Laboratory, the University of Arizona, and steel company Cleveland-Cliffs Inc. has developed a promising new zero-carbon, electrochemical process for producing steel.

The process is a novel molten salt electrolysis method that is low-cost, capable of achieving high rates, and uses environmentally benign chemicals.  The process does not use carbon at all.  Using molten salts, electrochemistry can be performed at moderately high temperatures rather than the temperatures of nearly 3000 degrees Fahrenheit used for conventional steelmaking.  The goal is to enable steel production that is both economically viable at an industrial scale and that is environmentally sustainable.

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Case Western Reserve leading research to develop zero-carbon, electrochemical process to produce iron metal as part of U.S. Department of Energy effort

Photo, posted January 11, 2017, courtesy of Kevin Casey Fleming via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Shrinking Glaciers And Methane | Earth Wise

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The Arctic region is warming much faster than the rest of the planet.  In fact, according to a study published last year in the journal Nature, the Arctic has been warming nearly four times faster than the rest of the globe during the last 43 years.  This rapid warming is leading to substantial reductions in sea ice, thawing of permafrost, shifts in wildlife populations, and changes in ocean circulation patterns, among other changes. 

According to new research recently published in the journal Nature Geoscience, shrinking glaciers in the warming Arctic are exposing bubbling groundwater springs, which could provide an underestimated source of methane, a potent greenhouse gas.  Methane is more than 25 times as potent as carbon dioxide at trapping heat in the atmosphere.

The study, which was led by researchers from the University of Cambridge and the University Centre in Svalbard, Norway, found large sources of methane gas leaking from groundwater springs unveiled by melting glaciers. 

As glaciers retreat in the Norwegian archipelago of Svalbard and leave behind newly exposed land, groundwater beneath the Earth seeps upward and forms springs. In 122 out of the 123 springs studied, the research team found that the water was highly concentrated with dissolved methane.  When the spring water reaches the surface, the excess methane can escape to the atmosphere. 

Researchers are concerned that additional methane emissions released by the Arctic thaw could dramatically increase human-induced global warming.  If this phenomenon in the Svalbard archipelago is found to be more widespread across the Arctic — where temperatures are quickly rising and glaciers melting — the methane emissions could have global implications. 

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The Arctic has warmed nearly four times faster than the globe since 1979

Shrinking Arctic glaciers are unearthing a new source of methane

Photo, posted October 22, 2022, courtesy of David Stanley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Renewables In China | Earth Wise

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A couple of years ago, China set an ambitious goal for renewable energy capacity – which includes wind, solar, hydroelectric, and nuclear power – for it to exceed fossil fuel capacity by 2025.  According to a recent report by Reuters, China has hit this goal two years ahead of schedule.  Renewables now make up 50.9% of the country’s power capacity.

The rapid growth in renewable capacity has largely been driven by investments in wind and solar megaprojects in the sparsely populated west of the country that export power to the manufacturing centers in the east.  China’s most recent 5-year plan calls for 570 gigawatts of wind and solar power to be installed over that period, which more than doubles its installed capacity.  The plan makes use of what it called “clean energy bases”, which utilize sandy and rocky deserts, other types of barren lands, and wastelands left behind by coal mining.  The largest clean energy bases make use of vast deserts in Inner Mongolia and Gansu.

One cautionary note is that power capacity refers to the maximum amount of electricity that a power plant can produce under ideal conditions.  Thus, for example, it refers to how much electricity a solar farm can generate at noon on a cloudless day.  So, the new figures from China don’t necessarily reveal how much electricity China is actually drawing from renewables.  In reality, China still gets a great deal of its power from coal.

China is the world’s largest emitter of carbon dioxide – more than twice as much as the United States, albeit from nearly 4 times the population.  The rapid growth of renewables is at least moving that country in the right direction.

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Fossil Fuels Now Account for Less Than Half of China’s Power Capacity

Photo, posted December 2, 2015, courtesy of IBM via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fungus And Carbon Storage | Earth Wise

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It is well-known that plants and trees store enormous amounts of carbon.  What has not been common knowledge is that the vast underground network of fungi across the world’s lands stores billions of tons carbon, roughly equivalent to 36% of yearly global fossil fuel emissions.

These mycorrhizal fungi form symbiotic relationships with almost all land plants.  The fungi transport carbon, converted by sugars and fats by plants, into soil.  They have been supporting life on land for at least 450 million years and form sprawling underground networks everywhere – even beneath roads, gardens, and houses – on every continent on earth.

An international team of scientists analyzed hundreds of studies looking at plant-soil processes to understand how much carbon is being stored by fungi on a global scale.  The findings, published in the journal Current Biology, revealed that over 13 billion tons of CO2 is transferred from plants to fungi each year, more than China emits annually.  This process transforms the soil beneath our feet to a massive carbon pool and constitutes the most effective carbon storage activity in the world.

Given that fungi have such a crucial role in mitigating carbon emissions, the researchers are recommending that fungi should be considered in biodiversity and conservation policies. More needs to be done in protecting the underground networks of mycorrhizal fungi. The UN has warned that human activities are degrading soils and that 90% of the world’s soils could be degraded by 2050.  Not only would this obviously be very bad for the productivity of crops and plants, but we now know this could be catastrophic for curbing climate change and rising temperatures.

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Fungi stores a third of carbon from fossil fuel emissions and could be essential to reaching net zero

Photo, posted May 28, 2023, courtesy of Geoff McKay via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Moss And Carbon Storage | Earth Wise

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All plants, including algae and cyanobacteria, carry out photosynthesis. During the process of photosynthesis, plants remove carbon dioxide from the air and release oxygen to the air.  As a result, plants play a crucial role in the fight against climate change. 

According to a new study recently published in the journal Nature Geoscience, mosses – those tiny plants often found on the ground or rocks – might be important antidotes to climate change.  The study, which was led by scientists from the University of New South Wales in Australia and the Institute of Natural Resources and Agrobiology in Spain, uncovered evidence that mosses have the potential to store a massive amount of carbon in the soil beneath them.

The researchers found that mosses sequester around seven billion tons more carbon in the soil than is stored in the bare patches of soil typically found near them.  To put that figure in perspective, that is six times the annual global carbon emissions caused by global land use change, which includes things like deforestation, urbanization, and mining.  The researchers also found that moss-covered soil possessed heightened levels of vital nutrients and fewer instances of soil-borne plant pathogens on average compared to moss-less soil.

Mosses cover an area of more than 3.6 million square miles, which is similar in size to Canada, and can thrive in challenging environments.  The widespread presence and hardiness of mosses is why they can have such a significant impact on soil biodiversity and carbon sequestration. 

The research team hopes future work will focus on understanding the role of all types of vegetation, not just mosses and trees, in capturing carbon.

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Study: Modest moss supports billions of tons of carbon storage

Photo, posted August 23, 2017, courtesy of Peter Handke via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Liquid Fuel From Sunshine | Earth Wise

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A key goal of artificial photosynthesis research is to be able to produce a useful liquid fuel using only carbon dioxide, water, and sunlight in a single step.  Such a so-called solar fuel would produce net zero carbon emissions and would be completely renewable.

Bioethanol has long been touted as a green alternative to fossil fuels, since it is made from plants rather than petroleum.  But producing it takes up agricultural land that could be used to grow food instead and there are emissions associated with many aspects of the process by which plant mass becomes fuel.

Researchers from the University of Cambridge in the UK have developed a so-called artificial leaf that produces ethanol or propanol – usable liquid fuels – in a single step.  They developed a copper and palladium-based catalyst that allows the artificial leaf to directly produce multicarbon complex chemicals.  Earlier versions of artificial leaves could make simple chemicals, such as syngas, which would then require additional processing to turn into high-density fuels.

The new device produces liquid fuel from carbon dioxide and water simply by shining sunlight on it.

At present, the artificial leaf is a proof-of-concept device that exhibits only modest efficiency.  The researchers are working to optimize the device’s light absorbers so that they can better make use of sunlight and to optimize the catalyst so that it can convert more of the sunlight into fuel.  In addition, the device needs to be scaled up so that it can produce large volumes of fuel.

All that being said, it is an important step towards people being able to do what plants have been doing for millions of years.

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Driving on sunshine: clean, usable liquid fuels made from solar power

Photo, posted March 23, 2015, courtesy of Astro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

The Upper Atmosphere Is Cooling | Earth Wise

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The part of the atmosphere closest to the Earth’s surface has been warming since the Industrial Revolution.  This warming is associated with increasing amounts of carbon dioxide as well as other human-made chemicals that have been changing the makeup of the atmosphere. Climate change is generally thought about in terms of the lowest regions of the atmosphere – known as the troposphere – where our weather happens.

But climate models also predict that another result of the changes to the makeup of the atmosphere is that most of the atmosphere up higher will get dramatically colder.  The same gases that are warming the bottom few miles of air are cooling the much greater expanses above that extend to the edge of space.

Recent satellite data has confirmed the accuracy of these models and provide further confirmation of the human fingerprint of climate change. The natural variability of weather that complicates climate models does not play a role in the upper atmosphere.

In the higher levels of the atmosphere, the effects of increasing levels of carbon dioxide are quite different.  In the thinner air up there, the heat trapped and re-emitted by CO2 does not bump into other molecules creating warming.  Instead, it escapes to space.  Combined with the trapping of heat at lower levels, the result is a rapid cooling of the upper atmosphere.

There are potential problems associated with the cooling upper atmosphere including that it is contracting.  The result is that the crowd of manmade objects in low orbit remains there longer, and there is a potential increased degradation of the ozone layer. 

The changes we are making to the atmosphere are having significant effects from the surface of the earth to the edge of space.

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The Upper Atmosphere Is Cooling, Prompting New Climate Concerns

Photo, posted August 18, 2021, courtesy of Arek Socha via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon-Negative Concrete | Earth Wise

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Concrete is a mainstay of modern civilization.  The world produces more than 4 billion tons of it each year and the process requires high temperatures, mostly obtained by burning fossil fuels.  The chemical reactions that produce concrete also produce large amounts of carbon dioxide.  In all, cement production is responsible for about 8% of total global carbon emissions by human activities.

This situation is the impetus for a wide range of research activities aimed at reducing the environmental impact of concrete production.  Researchers at Washington State University have recently developed a way of making carbon-negative concrete: a recipe for concrete that absorbs large amounts of carbon dioxide.

There have been attempts in the past to add biochar to concrete.  Biochar is a type of charcoal made from organic waste that sucks up carbon dioxide from the air.  In earlier attempts, even adding 3% of biochar would dramatically reduce the strength of the concrete.

The WSU researchers found that treating biochar with concrete washout wastewater makes it possible to add much more biochar to concrete without reducing its strength.  Mixing it with biochar adds calcium, which induces the formation of the mineral calcite, which in turn strengthens the concrete.

The researchers were able to add up to 30% biochar to their cement mixture.  Within a month, the resultant concrete was comparable in strength to ordinary concrete.  But at the same time, the biochar was able to absorb up to 23% of its weight in carbon dioxide from the air.  The new concrete is potentially the most environmentally friendly concrete ever developed.

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Researchers develop carbon-negative concrete

Photo, posted January 31, 2012, courtesy of Michael J. Nevins / U.S. Army Corps of Engineers via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Removing Carbon Dioxide Won’t Get the Job Done | Earth Wise

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Limiting global warming to no more than 1.5-2 degrees Celsius above pre-industrial levels is a crucial goal for humankind.  Countries, companies, and other organizations around the world have committed to achieving ‘net zero’ emissions.  This is distinct from zero emissions in that it includes removing carbon dioxide from the atmosphere to offset the amounts we are putting into it.  Carbon dioxide removal is increasingly touted as the way to achieve emission goals.  But it is a realistic strategy?  According to a recent paper by a leading climate scientist in the journal Nature, the answer in the short term is decidedly no.

In 2022, the world emitted 45 billion tons of carbon dioxide into the atmosphere.  Last year’s bipartisan Infrastructure Law earmarked $3.5 billion for developing four direct air capture hubs in the US.  Each of these is expected to eventually be able to extract a little over a million tons of CO2 from the air each year. These hubs combined would therefore remove about 52 minutes’ worth of the year’s emissions over the course of the year. 

The bottom line is that unless we drastically reduce emissions, all the carbon dioxide removal strategies combined will scarcely make a dent in the problem.

We will never be able to eliminate all sources of emissions, particularly from certain industries, and carbon dioxide removal will be a very important technology to address those emissions, but in the big picture, it is essential that the world decarbonizes as much as possible and as soon as possible.

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Carbon dioxide removal is not a current climate solution — we need to change the narrative

Photo, posted January 19, 2009, courtesy of Wladimir Labeikovsky via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Greenhouse Gases Continue To Rise | Earth Wise

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Despite all the focus on reducing emissions of greenhouse gases, there continues to be little progress toward actually accomplishing reductions.  A combination of growing populations, increasing industrialization in the developing world, and just plain reluctance on the part of many sectors of society to act, have all contributed to the continuing buildup of climate-altering gases in the atmosphere.

Levels of carbon dioxide, methane, and nitrous oxide – the three greenhouse gases produced by human activity that are the major contributors to climate change – all continued historically high rates of growth in 2022.

CO2 levels rose by 2.13 parts per million last year, roughly the same rate observed during the past decade.  The current level of 417 ppm is 50% higher than pre-industrial levels.  Increases of more than 2 ppm have occurred for 11 consecutive years.  Prior to 2013, there had never even been 3 years in row with increases of that size.

Methane levels increased by 14 parts per billion, the fourth largest increase over the past 40 years.  Methane levels in the atmosphere are now two-and-a-half times greater than their pre-industrial level. 

The third most significant greenhouse gas – nitrous oxide – also saw a large increase, reaching 24% above pre-industrial levels.

Carbon dioxide emissions are by far the most important contributor to climate change and the continuing widespread burning of fossil fuels is the primary source.  There are widespread intentions to reduce carbon dioxide emissions, but those intentions have not yet resulted in sufficient actions.

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Greenhouse gases continued to increase rapidly in 2022

Photo, posted May 16, 2014, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Storing Carbon Dioxide In The Ocean | Earth Wise

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Reducing the amount of carbon dioxide entering the atmosphere means either shutting down emission sources (primarily curbing the use of fossil fuels) or capturing the CO2 as it is emitted.  Capturing carbon dioxide from smokestacks and other point sources with high concentrations is relatively efficient and can make economic sense.  Removing it from the air, which even at today’s dangerously high levels contains only 400 parts per million, is difficult and energy intensive.  And even when it is removed, it then must be stored somewhere.

Researchers at Lehigh University have developed a novel way to capture carbon dioxide from the air and store it in what is effectively the infinite sink of the ocean.  The approach uses an innovative copper-containing filter that essentially converts CO2 into sodium bicarbonate (better known as baking soda.)  The bicarbonate can be released harmlessly into the ocean.

This technique has produced a 300 percent increase in the amount of carbon dioxide captured compared with existing direct air capture methods.   It does not require any specific level of carbon dioxide to work.  The filter becomes saturated with the gas molecules as air is blown through it.  Once this occurs, seawater is passed through the filter and the CO2 is converted to dissolved bicarbonate.  Dumping it into the ocean has no adverse effect on the ocean.  It doesn’t change the salinity at all, and the stuff is slightly alkaline, which will help reduce ocean acidification.

Reusing the filter requires cleaning it with a sodium hydroxide solution, which can be created from seawater using electricity generated by waves, wind, or sun.

The filter, called DeCarbonHIX, is attracting interest from companies based in countries around the world.

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Path to net-zero carbon capture and storage may lead to ocean

Photo, posted March 10, 2007, courtesy of Gail via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Concrete And Carbon | Earth Wise

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After water, concrete is the world’s second most consumed material.  It is the cornerstone of modern infrastructure.  Its production accounts for 8% of global carbon dioxide emissions.  The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement.  These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat.  However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide.  The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete.  The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly.  Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint.  In addition, the resulting concrete sets much more quickly.  It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Ocean-based Climate Intervention And Deep-sea Ecosystems | Earth Wise

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Deep-sea ecosystems cover more than 40% of the Earth.  These regions are some of the least well-known and understood areas of our planet but are home to numerous ecosystems.  The deep seas are already directly exposed to the effects of human-induced climate change but could potentially be greatly threatened by efforts to artificially counteract climate change.

A class of geoengineering solutions called ocean-based climate interventions are increasingly being claimed as promising ways to mitigate climate change.  Such interventions would remove carbon dioxide from the atmosphere and sequester it in the deep sea.  There is very little known about the impact of such efforts on ocean biogeochemistry and the biodiversity of ocean ecosystems.

One approach is direct CO2 injection into the deep ocean, which would sequester large amounts of it and reduce the concentration in the atmosphere.  However, too much carbon dioxide in the water is called hypercapnia, which can have serious consequences on marine life.

Other approaches include ocean fertilization – which is enhancing phytoplankton production at the surface, leading to their eventual deposition on the deep-sea floor – and crop waste deposition – which is deep-sea disposal of terrestrial crop waste. 

A multinational study led by the Scripps Institution of Oceanography warns that there needs to be much more research and governance before any such interventions ever take place.  The deep sea faces unprecedented threats from industrial fisheries, pollution, warming, deoxygenation, acidification, and other climate-related problems.  Ocean-based climate intervention represents yet another serious threat to the functioning of these essential ecosystems.

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HKU Marine Scientist contributes to research assessing the potential risks of ocean-based climate intervention technologies on deep-sea ecosystems

Photo, posted January 6, 2010, courtesy of Emrys Roberts via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pulling Carbon Dioxide Out Of Seawater | Earth Wise

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The world’s largest sink for carbon dioxide from the atmosphere is the ocean.  The world’s oceans soak up 30-40% of all the gas produced by human activities.  Dissolving carbon dioxide in water produces carbonic acid.   This is the reason that oceans are becoming increasingly acidic, which is causing serious damage to ocean ecosystems.

There are many efforts underway aimed at directly removing carbon dioxide from the air as a way to mitigate the effects of ongoing emissions.  But another possibility is to remove CO2 directly from ocean water.  Existing methods for doing it involve the use of expensive membranes and complex chemicals. The economics of such methods are quite unfavorable.

Recently, a team of researchers at MIT has identified what they claim is a truly efficient and inexpensive removal mechanism. It involves a reversible process based on membrane-free electrochemical cells.  Electrodes in the cells release protons that are introduced to seawater which drive the release of carbon dioxide dissolved in the water. The carbon dioxide can be collected and the processed water ends up being alkaline.

Running this process at a site that is already collecting seawater – such as at a desalination plant – would be an effective way to collect carbon dioxide as well as help mitigate ocean acidification.

Once the carbon dioxide is removed from the water, it still needs to be disposed of, just as is the case for other carbon removal processes.  It could be turned into useful chemicals or it could be stored in underground caverns.  But this approach is fairly unique in that the carbon dioxide has already been captured by the ocean.  The issue remains what to do with it.

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How to pull carbon dioxide out of seawater

Photo, posted January 19, 2016, courtesy of Judy Dean via Flickr.

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