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Marine carbon dioxide removal

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About 30% of the carbon dioxide emitted by human activity is absorbed by the oceans.  As a result, they are getting warmer and more acidic, and the currents that help shape global weather are shifting.  To try to reduce global warming, people want to be able to store even more carbon dioxide in the oceans without the negative effects of doing so.

There are multiple efforts across the globe to achieve effective marine carbon dioxide removal.  Some are based on sinking carbon-rich materials to the bottom of the sea.  This is the marine equivalent of capturing CO2 from the air and storing it underground.  Other efforts involve increasing the alkalinity of the ocean, which increases its ability to chemically react with carbon dioxide as well as lowers its acidity, which is desirable in many ways.

Running Tide, a U.S.-based company, has been dumping thousands of tons of wood-industry waste 190 miles off the coast of Iceland.  The company has also been experimenting with dumping algae and kelp and sinking it deep below the ocean.  Such materials on land either get burned or decay, in both cases releasing CO2 into the atmosphere.  On the deep-sea bottom, the carbon is trapped.

Other efforts involve pumping seawater through electrodialysis filter systems to remove excess acidity or adding alkaline rocks to increase water alkalinity.

All of these efforts are a form of geoengineering, and like proposed ideas to cool the atmosphere, pose potential risks.  There is no silver bullet to solve the climate crisis.  It will take a combination of many solutions to address the issue of excess carbon dioxide in the atmosphere.  Marine carbon dioxide removal is one of the solutions that may play a role.

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Scientists Are Trying to Coax the Ocean to Absorb More CO2

Photo, posted February 22, 2018, courtesy of Bobbie Halchishak/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Animals And Wildfires | Earth Wise

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More than a century of fire suppression strategies coupled with climate change has led to wildfires that are much larger and more frequent than those of the past.  A question that arises is what happens to the animals in a region when a massive wildfire sweeps through the landscape?

For the most part, we don’t have much information on what animals do when the flames are burning or in the immediate days after the fire has ended.  By chance, a group of researchers from the University of California, Berkeley, the University of California, Santa Barbara, and the University of Washington had the opportunity to get that kind of information.

The researchers had been studying a group of black-tailed deer where the 2018 Mendocino Complex Fire occurred.  That megafire torched more than 450,000 acres in Northern California, including the site where the researchers were studying the movements and feeding patterns of the deer.

The researchers had to evacuate the area during the fire, but their cameras, tracking collars, and other equipment continued to function.  They learned that of the 18 deer studied, all survived.  Deer that had to flee the flames returned home, even though many areas were completely burned and devoid of vegetation to eat.  In fact, most of the deer returned within hours of the fire’s end while trees were still smoldering.   The researchers continue to monitor the deer to look at the long-term effects of the fire.

The researchers speculate that loyalty to home is a tactic that likely helped the species survive past wildfires.  Smaller fires encourage new vegetation growth, a tasty treat for deer.  Whether the strategy will pay off as fires get more intense and more frequent remains to be seen. 

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After California’s 3rd-largest wildfire, deer returned home while trees were ‘still smoldering’

Photo, posted July 17, 2017, courtesy of C Watts via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaner Water Using Corn | Earth Wise

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Corn is the largest agricultural crop in the U.S., and it is also one of the most wasteful.  About half of the harvest ends up as stover – corn stalks, leaves, husks, and cobs – once the kernels are used for food.

Corn stover has relatively few commercial or industrial uses.  It can be used to produce biofuel, but that is not very energy efficient.  It is sometimes used as a low-quality livestock feed as well.  Mostly, it is just burned if it is used at all.

Researchers at the University of California Riverside have developed an energy-efficient way to make good use of stover by transforming it into activated carbon for use in water treatment.

Activated carbon – often called activated charcoal – is an organic material that is specially treated to contain millions of microscopic pores that make it highly absorbent.  It has many industrial uses, the most common of which is for filtering pollutants out of drinking water.  Most household water filters such as Brita filters as well as the ones built into refrigerators make use of activated carbon.

The Riverside researchers explored methods for producing activated carbon from charred corn stover and found that processing the material with hot compressed water – a process known as hydrothermal carbonization – produced highly absorbent activated carbon with superior properties compared to material produced by slow pyrolysis, where corn stover is charred at increasing temperatures over a long period of time.

According to the researchers, it is important to create approaches that convert waste into high-value materials, fuels, and chemicals in order to create new value streams and eliminate the environmental harm that comes from a so-called “take-make-dispose” economic model.

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Cleaner Water Through Corn

Photo, posted September 15, 2010, courtesy of the United Soybean Board / the Soybean Checkoff via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Fuel From Lignin | Earth Wise

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Lignin is an organic polymer that provides the rigid structure of plants and is what gives wood and bark their characteristic properties.  Lignin typically comprises between 20 and 35% of the mass of wood.  The two major substances extracted from trees, grasses, and other biomass materials are cellulose and lignin.  Cellulose is used to make paper, bioethanol, and other products, but lignin is largely unused because it is difficult to break down into useful substances such as feedstocks for fuels.  As a result, lignin is largely wasted.  Worldwide, some 50 million tons of lignin are produced from paper and bioethanol manufacturing each year and almost all of that is simply burned to generate heat.

Lignin can be broken down using pyrolysis techniques at high temperatures to create bio-oils, but those oils lack sufficient hydrogen and contain too much oxygen to be useful as fuels.  There is a process called hydrodeoxygenation that adds hydrogen and removes oxygen, but it requires high temperatures and very high pressures as well as producing char and tar that reduces the efficiency of the process.

Researchers at Georgia Tech recently published work describing a new process for turning lignin into useful products.  They developed a dual catalyst system of super-acid and platinum particles that adds hydrogen and removes oxygen from lignin bio-oil and makes it useful as a fuel and source of chemical feedstocks. 

The new process could help meet the growing demand for bio-based oils as well as helping the forest product, paper, and bioethanol industries by providing an additional revenue stream from what previously was a waste product.

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New Process Boosts Lignin Bio-oil as a Next-Generation Fuel

Photo, posted August 16, 2017, courtesy of evcabartakova via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plastic From Algae | Earth Wise

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Many researchers consider algae to be one of the best renewable resources for replacing fossil fuels and even as a food source.  The green microalgae Nannochloropsis salina is already a common source of omega-3 fatty acids that are sold as dietary supplements.  As a result, that algae strain is already grown on a large scale for the production of omega-3 products.

A group of researchers at UC San Diego has developed a way to make use of the waste stream from that production to create plastics and other useful products.  Currently, when the algae is processed to extract the omega-3 oil, leftover oils comprising more than 70% of the starting material are either thrown away or burned. 

The UCSD team has developed a process to purify and convert this waste stream into azelaic acid, which is a building block for flexible polyurethanes.   These materials have all kinds of commercial applications from flip-flops and running shoe soles to mattresses and yoga mats.

By analogy to the use of animals by native American tribes, the researchers wanted to “use the whole buffalo” in their solution for algae processing waste and therefore figured out how to convert heptanoic acid – another substance in the algae waste stream – into a food flavoring and fragrance.  The flavoring molecule is valued at over $500 per kilogram.

The work, published in the journal Green Chemistry, demonstrates that an algae-source waste stream has both the practical and economic potential to support production of polyurethanes.  The team is already working with shoe companies to commercialize the technology.  With mounting concern over petroleum-based plastic waste, renewable plastic made from algae is an attractive alternative.

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Researchers Turn Algae Leftovers into Renewable Products with Flare

Photo, posted November 8, 2006, courtesy of Adam Moore via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Deepwater Impacts Lingering

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On April 20, 2010, an explosion on the BP-owned Deepwater Horizon drilling rig released an estimated 210 million of gallons of oil into the Gulf of Mexico.  Some of the oil was recovered, burned, or dispersed at sea, while some washed up onto coastal shorelines. 

Now, more than nine years later, a long-term study suggests the oil is still affecting the salt marshes of the Gulf Coast.  A multi-institutional research team began sampling in the region once the spill was contained and continue their work to this day.

The researchers found that heavily-oiled marsh areas remained less healthy than less polluted sites more than six years after the spill.  They fear that complete recovery of these oil-soaked regions will likely take more than a decade. 

But the researchers also discovered that salt marsh grasses play a key role in coastal wetland recovery.  Two plants dominate healthy salt marshes in the Gulf: smooth cordgrass and black needlerush.  Single-celled, plant-like organisms known as benthic microalgae also abound in healthy salt marshes, as do many small invertebrates. 

In heavily-oiled areas, the researchers found that nearly all the plants died, and benthic microalgae and small invertebrate populations declined significantly.  Importantly, however, they also found that it was only after smooth cordgrass started its comeback in these areas that invertebrate populations began to recover.  They noted that these salt marsh grasses provide habitat, bind soil, slow water, facilitate colonization, and fuel the food web. 

Plants are the foundation of and play a crucial role in salt marshes.  The researchers hope these findings will help shape the mitigation strategies of any future oil spills. 

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Continuing impacts of Deepwater Horizon oil spill

Photo, posted April 21, 2010, courtesy of Deepwater Horizon Response via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Car Parts From Agricultural Waste

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A new bio-composite material made from date palm fiber biomass could be used to produce sustainable, lightweight and low-cost parts for the automobile and marine industries.

A team of researchers from the UK has developed a date palm fiber polycaprolactone composite that is completely biodegradable, renewable,sustainable and recyclable, in contrast to synthetic composite materials reinforced by glass and carbon fibers. The team tested the mechanical properties of the material and found that it achieved better low-velocity impact resistance than traditional man-made composites.

The idea would be to use the material in non-structural auto parts such as car bumpers and door linings.   The result would be to reduce the weight of vehicles, contributing to less fuel consumption and lower emissions.  The new material can be produced using less energy than glass and carbon fibers and is biodegradable and therefore easier to recycle.

Date palm fibers are one of the most available natural fibers in many parts of the world.  The trees produce a large quantity of agricultural waste, which is mostly burned or land-filled,causing serious environmental problems.

Convincing industry to use a new class of materials such as natural-fiber reinforced composites is challenging.  First it is necessary to obtain consistent,reliable properties from the material. Then the industries need to work closely with the developers to test the materials and convince themselves of the viability of using them.  The team, led by researchers at the University of Portsmouth, has been working with industry to test the viability of parts made from a variety of other sustainable materials as well including flax, hemp, and jute.  Someday, our cars may have bumpers made from agricultural waste.

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Agricultural waste drives us closer to greener transport

Photo, posted October 27, 2017, courtesy of David Stanley via Flickr. 

Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)