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toxic pollutant

Tracking atmospheric mercury

May 13, 2025 By EarthWise Leave a Comment

A cheap way to track atmospheric mercury levels

Atmospheric mercury is a toxic pollutant released into the air from natural sources—such as volcanoes and wildfires—and from human activities like coal burning and gold mining.  Once in the atmosphere, mercury can travel long distances before settling onto land or into water, transforming into toxic forms that threaten ecosystems and human health.

But tracking atmospheric mercury is a costly and challenging endeavor, requiring specialized equipment and trained personnel. Active monitors, which pump air to collect mercury, are expensive and need electricity, while passive samplers, using activated charcoal for remote areas, cost up to $100 each.

Researchers from Cornell University have found a cheap method for tracking toxic atmospheric mercury near gold mining sites throughout the Global South: wild fig trees.  In the study, which was conducted in the Peruvian Amazon and recently published in the journal Frontiers in Environmental Science, the research team found that the rings in wild fig trees can serve as natural archives of atmospheric mercury, capturing and preserving historical pollution levels over time.

The technique itself is not actually new.  Previous studies have used tree rings to track mercury pollution from coal combustion, particularly in Canada. But the research team wanted to test this method in regions of the Global South, where mercury emissions from gold mining are widespread.

According to the research team, wild fig trees might soon serve as an important biomonitoring tool, helping scientists better understand how mercury disperses across landscapes and through time.

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Tree rings track atmospheric mercury cheaply

Photo, posted November 13, 2012, courtesy of Steve Kessler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Converting A Toxin Into An Industrial Chemical | Earth Wise

January 16, 2020 By EarthWise Leave a Comment

Converting toxin into industrial chemical

Nitrogen dioxide is a prominent air pollutant produced by internal combustion engines burning fossil fuels as well as by a variety of industrial processes.  It is a toxic material associated with a number of respiratory illnesses. 

Researchers at the University of Manchester in the UK along with an international team of scientists have developed a new advanced material that can convert nitrogen dioxide from an exhaust gas stream into useful industrial chemical using only water and air.

The material is a metal-organic framework (or MOF) that provides a selective, fully reversible, and repeatable capability to capture nitrogen dioxide.  MOFs are tiny three-dimensional structures that are porous and can trap gases inside as though there were tiny cages.  MOFs have enormous amounts of surface area for their size.  One gram of material can have a surface area as large as a football field.

The material, named MOF-520, can capture nitrogen dioxide at ambient temperatures and pressures and even at low concentration and during flow in the presence of moisture, sulfur dioxide, and carbon dioxide.  Such conditions are typical of the exhaust of internal combustion engines. In fact, the process works best at the typical temperature of automobile exhausts.

Once the nitrogen oxide is absorbed, treating the material with water in air converts it into nitric acid and restores the MOF for additional use.  Nitric acid is the basis of a multi-billion dollar industry with uses including agricultural fertilizers, rocket propellant, and nylon.  Thus, there is great potential for recouping the costs of using the MOF technology and even profiting from it.

It would be great to convert a toxic pollutant into valuable industrial chemicals.

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Clean air research converts toxic air pollutant into industrial chemical

Photo courtesy of the University of Manchester.

Earth Wise is a production of WAMC Northeast Public Radio.

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