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titanium oxide

A better way to produce green hydrogen

September 9, 2024 By EarthWise Leave a Comment

Hydrogen has great potential as a fuel and an energy carrier for many applications.  Burning it or consuming it in fuel cells does not produce carbon emissions.  As a result, there has long been the vision for a future hydrogen economy.  Whether the hydrogen economy would ever come about given how various other technologies have evolved over time is questionable.  But regardless, hydrogen is valuable for many industrial and commercial applications including the manufacture of ammonia and the refining of metals.

Hydrogen is produced in industrial quantities from natural gas by a carbon-dioxide-producing process known as methane-steam reforming.  To take its place as a green energy source, hydrogen needs to be produced by splitting water into its constituent oxygen and hydrogen components by the process of electrolysis. 

The problem is economic.  Methane-steam reforming produces hydrogen at a cost of about $1.50 per kilogram.  Green hydrogen costs about $5 a kilogram.

Researchers at Oregon State University have developed a new photocatalyst that enables the high-speed, high-efficiency production of hydrogen.  The material, called RTTA, is a metal organic framework containing ruthenium oxide and titanium oxide.  Ruthenium oxide is expensive, but very little is needed.  For industrial applications, if the catalyst shows good stability and reproducibility, the cost of the small amount of this exotic material becomes less important.

The photocatalyst, when exposed to sunlight, quickly and efficiently splits water yielding hydrogen.  The Oregon State discovery has real potential.

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Oregon State University research uncovers better way to produce green hydrogen

Photo, posted July 7, 2023, courtesy of Bill Abbott via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Sunscreen And Coral Reefs | Earth Wise

May 18, 2021 By EarthWise Leave a Comment

Toxic sunscreens are killing corals

The dangers of overexposure to UV solar radiation have led to the extensive production and use of sunscreen products.  It is generally understood that many of the chemical compounds used in sunscreen products have toxic effects on marine organisms, but research in this area is relatively limited.

There are estimates that as many as 82,000 kinds of chemicals from personal care products have made their way into the world’s oceans.  In 2015, it was estimated that around 14,000 tons of sunscreen are ending up in the world’s coral reefs per year and causing irreparable damage.

Eighty-five percent of the Caribbean’s coral reefs died before the turn of the century, not as a result of global warming, but because of pollution.  Oxybenzone and octinoxate are two of the common sunscreen ingredients that are most toxic to corals.  Preservatives like parabens are also toxic.

There are much safer sunscreens such as those based on zinc oxide or titanium oxide.  In some places, such eco-friendly sunscreens are mandatory.  Sunscreens with SPF values above 30 contain a higher percentage of chemicals and have been shown to not really provide any more protection than SPF 30 products.

Apart from the choice of sunscreen product, if one really wants to reduce the negative impact sunscreen has on reefs and marine life, wearing sun-protective clothing such as rash-guards will allow the use of much less sunscreen and therefore result in less of it entering the ocean.

Products that can help protect against the harmful effects of UV radiation on human health are extremely important, but it is also important to identify and quantify the risks associated with these products to reef ecosystems.

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How to Know If Your Sunscreen Is Killing Coral Reefs — and the Brands to Try Instead

Impacts of sunscreen on coral reefs needs urgent attention, say scientists

Photo, posted January 11, 2015, courtesy of Elch Korallen via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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