room temperature

Fertilizer from thin air

January 16, 2025 By EarthWise Leave a Comment

Ammonia is one of the largest-volume synthetic chemicals produced in the world. Globally, manufacturing plants produce about 200 million tons of it each year. About 70% of ammonia is used to produce fertilizers.

Most ammonia is produced using the Haber-Bosch process, which converts hydrogen and nitrogen into ammonia. The process is energy-hungry, running at over 900 degrees Fahrenheit, and therefore results in lots of greenhouse gas emissions – about 1% of the world’s annual CO2 emissions.

Researchers at Stanford University and King Fahd University in Saudi Arabia have developed a prototype device that can produce ammonia using wind energy to draw air through a mesh. The method allows sustainable production of ammonia using the nitrogen in the air.

The process gets nitrogen from the air along with hydrogen from water vapor. A mesh coated with catalysts facilitates the necessary chemical reactions. The process operates at room temperature and standard atmospheric pressure, eliminating the need for the high temperatures and high pressures of the Haber-Bosch process.

In principle, farmers could run a portable device onsite, eliminating the need to purchase and ship fertilizer from a manufacturer.

The device is two or three years away from being market ready. The developers are designing increasingly large mesh systems to produce greater quantities of ammonia. Ammonia has more uses beyond fertilizers including its use as an energy carrier that can store and transport energy more efficiently than hydrogen gas.

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New device produces critical fertilizer ingredient from thin air, cutting carbon emissions

Photo, posted September 2, 2013, courtesy of Chafer Machinery via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Recyclable Wind Turbines | Earth Wise

January 1, 2021 By EarthWise Leave a Comment

The blades of modern wind turbines can be longer than the wing of a Boeing 747. Their useful lifetime is perhaps 20 years and after that, they can’t just be hauled away. They end up being cut up with special industrial saws to create pieces small enough to be strapped to a tractor-trailer. Then, they end up in landfills. There are thousands of blades being removed each year and those numbers are growing.

Wind turbine blades are currently manufactured using thermoset resin, which cannot be recycled. It is also energy-intensive and manpower-intensive to produce.

Researchers at the National Renewable Energy Laboratory in partnership with Arkema Inc of Pennsylvania have demonstrated the feasibility of using thermoplastic resin instead to make wind turbine blades. That material can be recycled and can also enable longer, lighter-weight, and lower-cost blades. Using thermoplastic could also allow manufacturers to build blades on site, alleviating the problems of transporting ever larger turbine blades.

Current blades are made primarily of composite materials like fiberglass infused with thermoset resin. The manufacturing process requires additional heat to cure the resin, which adds cost and time. Thermoplastic resin cures at room temperature and requires less labor. With regard to recycling, thermoplastic resin, when heated above a certain temperature, melts into its original liquid resin and can be reused.

NREL has demonstrated the feasibility of the thermoplastic resin system by manufacturing nearly identical blades using both the standard materials and the thermoplastics. NREL has also developed a technoeconomic model to evaluate the cost benefits of using thermoplastic resin.

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News Release: NREL Advanced Manufacturing Research Moves Wind Turbine Blades Toward Recyclability

Photo, posted June 28, 2008, courtesy of Patrick Finnegan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Palm Oil Replacement | Earth Wise

December 15, 2020 By EarthWise Leave a Comment

In the 1990s, cardiovascular health issues associated with partially hydrogenated oils containing harmful trans fats became a focus of great concern. As a result, food companies looked for substitutes and the alternative they identified was palm oil. Its ability to remain solid at room temperature made it well suited for many food applications. Unfortunately, that property stems from its high saturated fat content, which means it also increases the risk of coronary heart disease.

The widespread use of palm oil has also caused significant environmental problems. Palm oil plantations have replaced millions of acres of tropical forests, destroying the habitat for numerous species and threatening biodiversity.

Other potential replacements for partially hydrogenated oils such as coconut oil tend to be more costly, limited in supply, and also high in saturated fats.

Food scientists at the University of Guelph in Ontario, Canada, recently demonstrated the use of enzymatic glycerolysis (EG) to turn liquid vegetable oils into solid fats. Their process is able to produce solid fats with the textural and structural properties desired by consumers.

The process is fairly simple, relatively easy to scale up, and is amenable to smaller food production or even local production. Using it would enable food producers to use all sorts of readily available vegetable oils that can be produced in parts of the world that are not necessarily tropical regions.

Palm oil use is not going to go away, but this work may point a way to help slow down the destruction of ecosystems and animal habitats as well lead to more sustainable and healthy food sources.

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U of G Food Scientists Find Palm Oil Alternative That’s Good for Human, Planet Health

Photo, posted February 21, 2010, courtesy of Craig Morey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Room-Temperature Superconductor | Earth Wise

November 18, 2020 By EarthWise Leave a Comment

One of the Holy Grails of science has apparently been found: a room-temperature superconductor. In a paper recently published in Nature, scientists from the University of Rochester and collaborators announced that they had observed superconductivity at 59 degrees Fahrenheit in an exotic material they produced in the laboratory.

Superconductivity is a phenomenon occurring in certain materials characterized by the total absence of electrical resistance. Current flowing in a closed loop of superconducting wire can go on forever. Superconductors have other unique characteristics as well, all of which combine to make them quite useful in a number of applications. Superconductors are used in high-powered magnets in particle accelerators and in MRI machines. They continue to be developed for use in electrical power transmission, energy storage, communication filters, magnetic sensors, and more.

The problem with superconductors is that they only work at very low temperatures. For most of a century – after superconductivity was discovered in 1911 – those temperatures were very close to absolute zero: 459 degrees below zero Fahrenheit. (In the late 1980s, so-called high-temperature superconductors were discovered. Those materials superconduct at the temperature of liquid nitrogen: about 320 degrees below zero).

The dream has been to find a superconductor that works at ambient temperatures. The Rochester team has produced tiny amounts of a mysterious combination of hydrogen, carbon, and sulfur which, when subjected to extraordinarily high pressures (over 2 million atmospheres), superconducts at the temperature of a pleasant fall day.

There is no practical value for this first room-temperature superconductor, but it proves that superconductivity can exist at ambient temperature. Once something is shown to exist at all, there is reason to hope that it can occur in ways that are easier and more practical to attain.

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First room-temperature superconductor excites — and baffles — scientists

Photo, posted June 18, 2013, courtesy of Oak Ridge National Laboratory via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Super-Enzyme For Breaking Down Plastic | Earth Wise

November 13, 2020 By EarthWise Leave a Comment

The problems caused by plastic waste continue to grow. Plastic pollution is everywhere, from the Arctic to the depths of the ocean. We consume microplastics in our food and breathe them in the air. It is very difficult to break down plastic bottles into their chemical constituents in order to make new ones from old ones. Therefore, we continue to produce billions of single-use plastic bottles, creating more and more new plastic from oil each year.

Scientists at the University of Portsmouth in the UK have developed a new super-enzyme that degrades plastic bottles six times faster than before. They believe that the new enzyme could be used for plastic recycling within a year or two.

The super-enzyme was derived from bacteria that naturally have the ability to eat plastic. The researchers engineered it by linking two separate enzymes, both of which were found in a plastic-eating bug discovered in a Japanese waste site in 2016. They revealed an engineered version of the first enzyme in 2018, which started breaking down plastic in a few days. They had the idea that connecting two enzymes together would speed up the breakdown of plastic. Such linkage could not happen naturally in a bacterium.

Carbios, a French company, announced a different enzyme in April that can degrade plastic bottles within 10 hours but requires heating above 160 degrees Fahrenheit. The new super-enzyme works at room temperature.

The team is now examining how the enzymes can be tweaked to make them work even faster. Meanwhile, they plan to work in partnership with companies like Carbios, to bring super-enzymes for breaking down plastics into commercial use.

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New Super-Enzyme Can Break Down Plastic at Rapid Pace

Photo, posted March 24, 2017, courtesy of the USFWS – Pacific Region via Flickr. Photo credit: Holly Richards/USFWS.

Earth Wise is a production of WAMC Northeast Public Radio.