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Lampshades And Indoor Air Pollution | Earth Wise

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We mostly think of air pollution as an outdoor problem.  Common sources of air pollution include emissions from vehicles, byproducts of manufacturing and power generation, and smoke from wildfires.  What we don’t often spend a lot of time thinking about is indoor air quality. 

Indoor air pollution refers to harmful pollutants within buildings and structures, which can lead to a myriad of health issues.  Sources of indoor air pollution include smoke from tobacco products, as well as volatile organic compounds (VOCs), including acetaldehyde and formaldehyde, emitted from things such as paints, cleaning products, plastics, and cooking. 

A team of scientists from South Korea’s Yonsei University has developed a special coating that when applied to lampshades can convert pollutants into harmless compounds.  Composed of titanium dioxide and a small amount of platinum, this thermocatalyst can be applied to the inside surface of a lampshade and is triggered to break down VOCs when warmed by the lamp’s existing incandescent or halogen bulb.

In lab tests, the coating was applied to the inside of an aluminum lampshade, warmed by a halogen bulb, and then placed into a sealed chamber containing air and acetaldehyde gas.  The researchers found that the material quickly converted the gas into acetic acid, then into formic acid, and finally into carbon dioxide and water. The scientists are now looking for ways to extend the pollutant-destroying-lampshade concept to LED lightbulbs. 

The findings offer a promising and eco-friendly solution to improve indoor air quality and reduce the health risks associated with prolonged exposure to VOCs. 

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Clever coating turns lampshades into indoor air purifiers

Photo, posted March 21, 2009, courtesy of Levent Ali via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Aluminum In Batteries | Earth Wise

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Batteries are playing a bigger and bigger role in our lives.  Apart from their use in ubiquitous smartphones, laptops, and other devices, millions of electric vehicles are hitting the roads, and utilities are installing giant banks of batteries to store energy generated by wind and solar farms.

The necessary characteristics of batteries are high energy density and stability.  The latter is needed so that batteries can be safely and reliably recharged thousands of times.  For decades, lithium-ion batteries have been the go-to for all these modern battery applications.  And they have gradually gotten better and cheaper all the time.  But the improvements are getting smaller, and the price reductions have limits.

For these reasons, researchers are always looking for batteries with higher energy density – so that, for example, electric cars can drive farther on a charge – and that can be made more cheaply, are not flammable, and are very stable.

Since the 1970s, researchers have investigated the use of aluminum for the anode of batteries because its properties would allow more energy to be stored.  However, when used in lithium-ion batteries, aluminum developed fractures and failed after a few cycles.

Researchers at Georgia Tech University have developed a type of aluminum foil with small amounts of other materials that create specific microstructures.  Used in battery anodes, this material does not degrade and appears to be a path to a better battery.  When incorporated into a solid-state battery that does not contain the flammable liquid found in standard lithium-ion batteries, the result is a battery that checks most of the boxes in the search for a better battery.

Much more work is needed to assess the potential for the aluminum-based battery, but it looks very promising.

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Aluminum Materials Show Promising Performance for Safer, Cheaper, More Powerful Batteries

Photo, posted August 27, 2019, courtesy of Marco Verch via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Ocean-based Climate Intervention And Deep-sea Ecosystems | Earth Wise

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Deep-sea ecosystems cover more than 40% of the Earth.  These regions are some of the least well-known and understood areas of our planet but are home to numerous ecosystems.  The deep seas are already directly exposed to the effects of human-induced climate change but could potentially be greatly threatened by efforts to artificially counteract climate change.

A class of geoengineering solutions called ocean-based climate interventions are increasingly being claimed as promising ways to mitigate climate change.  Such interventions would remove carbon dioxide from the atmosphere and sequester it in the deep sea.  There is very little known about the impact of such efforts on ocean biogeochemistry and the biodiversity of ocean ecosystems.

One approach is direct CO2 injection into the deep ocean, which would sequester large amounts of it and reduce the concentration in the atmosphere.  However, too much carbon dioxide in the water is called hypercapnia, which can have serious consequences on marine life.

Other approaches include ocean fertilization – which is enhancing phytoplankton production at the surface, leading to their eventual deposition on the deep-sea floor – and crop waste deposition – which is deep-sea disposal of terrestrial crop waste. 

A multinational study led by the Scripps Institution of Oceanography warns that there needs to be much more research and governance before any such interventions ever take place.  The deep sea faces unprecedented threats from industrial fisheries, pollution, warming, deoxygenation, acidification, and other climate-related problems.  Ocean-based climate intervention represents yet another serious threat to the functioning of these essential ecosystems.

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HKU Marine Scientist contributes to research assessing the potential risks of ocean-based climate intervention technologies on deep-sea ecosystems

Photo, posted January 6, 2010, courtesy of Emrys Roberts via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A New Method of Refrigeration | Earth Wise

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Salting roads before winter storms is a familiar sight in the Northeast.  The purpose is to change the temperature at which ice can form on the road.  The underlying concept has formed the basis of a new method of refrigeration that has been dubbed “ionocaloric cooling.”

It is described in a paper published in the journal Science by researchers at the Lawrence Berkeley National Laboratory.  The method takes advantage of how energy in the form of heat is either stored or released when a material changes phase – such as water changing from ice to liquid and vice versa.  Melting absorbs heat from the surroundings while freezing releases heat.  An ionocaloric refrigerator makes use of this phase and temperature change using an electrical current to add or remove ions provided from a chemical salt.

The potential is to make use of this refrigeration cycle instead of the vapor compression systems in present-day refrigerators, which make use of refrigerant gases that are greenhouse gases, many of which very powerful ones.  The goal is to come up with a system that makes things cold, works efficiently, is safe, and doesn’t harm the environment. 

There are a number of alternative refrigeration systems under development that make use of a variety of mechanisms including magnetism, pressure, physical stretching, and electric fields.  Ionocaloric cooling uses ions to drive solid-to-liquid phase changes.

Apart from some very promising theoretical calculations of the system’s potential, the researchers have also demonstrated the technique experimentally.  They have received a provisional patent for the technology and are continuing to work on prototypes to demonstrate its capabilities and amenability to scaling up.

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Berkeley Lab Scientists Develop a Cool New Method of Refrigeration

Photo, posted October 29, 2021, courtesy of Branden Frederick via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Promising Malaria Vaccine | Earth Wise

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Malaria is a parasitic disease transmitted through the bite of female Anopheles mosquitoes.  Although the disease is both preventable and treatable, an estimated 435,000 people die of it each year, with the majority being children younger than five.  Over 90% of all malaria cases and deaths occur in Africa.

The battle against malaria has mostly centered around the use of bed nets, insecticide spraying and antimalarial drugs.  To date, there has not been an effective malaria vaccine available.

That may finally be changing.  The first vaccinations have begun in Mali in a phase III trial of a malaria vaccine developed by the University of Oxford.  The Oxford vaccine showed an efficacy of 77% over 12 months in a phase IIb trial and the hope is that the phase III trial will lead to the licensing of the vaccine in 2023. 

Oxford is partnering with the Serum Institute of India for the manufacturing of the vaccine in order to be able to produce high volumes of low-cost vaccine and provide access to countries where it is required the most.  The Serum Institute has committed to the production of more than 200 million doses per year once the vaccine is licensed for use, which will be an adequate supply for children most at risk of malaria in sub-Saharan Africa.

The World Health Organization Malaria Vaccine Technology Roadmap has a goal of a malaria vaccine with at least 75% efficacy.  Such a vaccine is needed in order to reach the WHO’s goal of reducing malaria deaths by at least 90% by 2030.

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Promising malaria vaccine enters final stage of clinical testing in West Africa

Photo, posted June 9, 2018, courtesy of Mario Yordanov via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Improving Solar Cells With Human Hair | Earth Wise

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Researchers at the Queensland University of Technology in Australia have been able to improve the performance of perovskite solar cells using material made from human hair.

Perovskite solar cells are an up-and-coming technology that offers the possibility of making solar cells less expensive, more efficient, and flexible so that there could be solar-powered clothing, backpacks, or even tents for camping.  While the technology has been shown to be as effective in converting sunlight to electricity as currently available silicon technology, it faces problems with stability and durability.

The Australian research centered on the use of carbon nanodots to improve perovskite solar cell performance.  The nanodots were created in a rather unique way.  The carbon came from hair scraps from a Brisbane barbershop that were first broken down and then burned at nearly 500 degrees Fahrenheit. 

By adding a solution of the carbon nanodots into the process of making the perovskites, the dots formed a wave-like layer in which the perovskite crystals in the cells are surrounded by the carbon dots.  It serves as a protective layer, essentially a kind of armor, for the active portions of the material.

The result was solar cells with a higher power conversion efficiency and greater stability.  The researchers did not explain why they chose human hair as the source of carbon, but it does make for an interesting sidelight to the promising research.

Perovskite solar cells could be very important for spacecraft applications where reducing weight is paramount.  But in order to be able to use them for this purpose, perovskite solar cells will need to be able to cope with the extreme radiation and temperature variations in space.

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Carbon dots from human hair boost solar cells

Photo, posted October 3, 2009, courtesy of Arktoi via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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