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polyethylene

A Better Way To Recycle Plastics | Earth Wise

November 10, 2022 By EarthWise Leave a Comment

The global accumulation of plastic waste is an ever-growing problem.  At least five billion tons of the stuff has accumulated on land and sea and is even showing up in the bodies of animals and humans.  Recycling plastic instead of making even more of it seems like an essential thing to do but it has proven to be extremely challenging.

The main problem is that plastics come in many different varieties and the ways of breaking them down into a form that can be reused are very specific to each type of plastic.  Sorting plastic waste by plastic type is extremely impractical at large scale.  Certainly, most consumers can’t do it themselves.  As a result, most plastic gathered in recycling programs ends up in landfills.

New research at MIT has developed a chemical process using a catalyst based on cobalt that is very effective at breaking down a variety of plastics, including polyethylene and polypropylene, which are the two most widely produced plastics.   The MIT process breaks plastics down into propane.  Propane can be used as a fuel or as a feedstock for making many different products, including new plastics.

Plastics are hard to recycle because their long-chain molecules are very stable and difficult to break apart.  Most chemical methods for breaking their chemical bonds produce a random mix of different molecules which would somehow have to be sorted out in order to be useful for anything.

The new process uses a catalyst called a zeolite that contains cobalt nanoparticles.  The catalyst selectively breaks down various plastic polymer molecules and turns more than 80% of them into propane.

The researchers are still studying the economics and logistics of the method, but it looks quite promising.

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New process could enable more efficient plastics recycling

Photo, posted April 25, 2016, courtesy of NOAA Coral Reef Ecosystem Program via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Humans And Microplastics | Earth Wise

April 13, 2022 By EarthWise Leave a Comment

Microplastics impact on human health

While plastic comes in all different shapes and sizes, those that are less than five millimeters in length are called microplastics.  Primary sources of microplastics include microfibers from clothing, microbeads, and plastic pellets (known as nurdles).  Secondary sources of microplastics come from larger plastic debris, like bottles and bags, that degrades into smaller bits over time. 

Microplastic pollution can be found everywhere on earth, from the top of the tallest mountains to the bottom of the deepest oceans.  Microplastics are in the food we eat, the water we drink, and the air we breathe. 

According to research recently published in the journal Exposure & Health, humans ingest an average of five grams of plastic particles per week. This is roughly equivalent to the weight of a credit card.  The plastic particles are trafficked in via food, such as seafood and salt in particular, as well as water.  In fact, those who rely on plastic bottled water for their drinking needs ingest an additional 1,700 plastic particles each week.   

Microplastics have also been detected in human blood for the first time.  According to new research recently published in the journal Environment International, scientists detected microplastics in nearly 80% of the people they tested. 

Half of the blood samples contained PET plastic, which is commonly used for drinking bottles.  One third of the blood samples contained polystyrene plastic, which is often used for food packaging.  One quarter of the blood samples contained polyethylene plastic, which is used to make things like shopping bags and detergent bottles. 

With plastic production predicted to double by 2040, more research is urgently needed to understand how ingesting microplastics affects human health.

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Health risk due to micro- and nanoplastics in food

Microplastics found in human blood for first time

Discovery and quantification of plastic particle pollution in human blood

Photo, posted November 3, 2012, courtesy of Laura via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Sustainable Polymer From Wood | Earth Wise

February 24, 2021 By EarthWise Leave a Comment

A step closer to making plastics more sustainable

Scientists from the University of Bath in the UK have developed a sustainable polymer using xylose, a sugar found in wood.

The new polymer is a member of the polyether family.  It could be used in a variety of applications, including being a building block for polyurethane, used for example in mattresses and shoe soles. It could also be a bio-derived alternative to polyethylene glycol, a chemical widely used in biomedicine, or in polyethylene oxide, which is sometimes used as an electrolyte in batteries.

Xylose, also known as wood sugar, is one of the most abundant carbohydrates on earth, second only to glucose. Apart from comprising 5-20% of hardwoods, xylose is a major component of straw, corncobs, and many other plant materials.

The new polymer could reduce reliance on crude oil products and its properties can be easily controlled to make the material flexible or crystalline.  Added functionality could be added to it by binding other chemical groups such as fluorescent probes or dyes to the sugar molecule for biological or chemical sensing applications.

Tweaking the physical and chemical properties of bio-derived polymers has previously been a very difficult thing to do.  The Bath researchers discovered that combining two mirror-image chemical forms of xylose results in a stronger and more adaptable material.  They have filed a patent for their technology and are seeking industrial collaborators for further development.

The reliance of plastics and polymers on fossil fuels is a major problem.  Bio-derived polymers, such as this new one, are an important part of the effort to make plastics sustainable.

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Scientists make sustainable polymer from sugars in wood

Photo, posted January 25, 2017, courtesy of Keith Double via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Keep Track Of Your LEGOs | Earth Wise

April 9, 2020 By EarthWise Leave a Comment

plastics in the ocean

Plastics in the ocean are a global problem that has attracted a great deal of attention.  Most of the concern surrounds grocery bags, bottles, six-pack rings, and similar items.  Recent research looked at another source of plastic pollution:  LEGOs.

According to environmental scientists at the University of Plymouth in the United Kingdom, it can take more than a thousand years for LEGO bricks to break down in the ocean.  The iconic toys are made from a strong plastic called acrylonitrile butadiene styrene or ABS.  Pieces of LEGOs are commonly found in ocean trash hotspots and wash up on shores across the globe by the thousands.

LEGOs are one of the most popular children’s toys in history and part of what makes them so popular is their durability.  Barefooted parents stepping on one on the floor in a dark room can attest to that fact.  But the full extent of their durability came as a surprise to the researchers.

The scientists analyzed pieces of weathered LEGOs collected from beaches, confirmed their age, and compared them to unweathered LEGOs from the 70’s and 80’s.  They were able to determine the extent to which LEGOs had been worn down by ocean waves, sand, and salt over time.  And it was surprisingly little.

LEGO has acknowledged the environmental impact of its products and has launched a goal to make its bricks from more sustainable sources such as sugarcane-based polyethylene by 2030, as well as improve its efforts to recycle and reuse old LEGO plastic.

Meanwhile, we should all we careful of where our old LEGOs end up.

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LEGO Bricks Could Linger in the Ocean for 1,300 Years, Study Finds

Photo, posted August 24, 2015, courtesy of Juan Luis via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Worms That Eat Plastic

June 7, 2017 By EarthWise

https://earthwiseradio.org/wp-content/uploads/2017/06/EW-06-07-17-Worms-That-Eat-Plastic.mp3

Plastics clogging up our landfills and polluting our oceans are a scourge of modern life and we struggle with ways to combat this growing problem.  The biggest issue is that most plastics are simply not biodegradable.   Polyethylene, the common plastic found in shopping bags and numerous other products, takes between 100 and 400 years to degrade in a landfill.

[Read more…] about Worms That Eat Plastic

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