chemical reactions

Capturing hot carbon dioxide

December 13, 2024 By EarthWise Leave a Comment

Decarbonizing industries like steel and cement is a difficult challenge. Both involve emitting large amounts of carbon dioxide both from burning fossil fuels and from intrinsic chemical reactions taking place. A potential solution is to capture the carbon dioxide emissions and either use them or store them away. But this sort of carbon capture is not easy and can be quite expensive.

The most common method for capturing carbon dioxide emissions from industrial plants uses chemicals called liquid amines which absorb the gas. But the chemical reaction by which this occurs only works well at temperatures between 100 and 140 degrees Fahrenheit. Cement manufacturing and steelmaking plants produce exhaust that exceeds 400 degrees and other industrial processes produce exhaust as hot as 930 degrees.

Costly infrastructure is necessary to cool down these exhaust streams so that amine-based carbon capture technology can work.

Chemists at the University of California, Berkeley, have developed a porous material – a type of metal-organic framework – that can act like a sponge to capture CO2 at temperatures close to those of many industrial exhaust streams. The molecular metal hydride structures have demonstrated rapid, reversible, high-capacity capture of carbon dioxide that can be accomplished at high temperatures.

Removing carbon dioxide from industrial and power plant emissions is a key strategy for reducing greenhouse gases that are warming the Earth and altering the global climate. The captured CO2 can be used to produce value-added chemicals or can be stored underground or chemically-reacted into stable substances.

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Breakthrough in capturing ‘hot’ CO2 from industrial exhaust

Photo, posted March 3, 2010, courtesy of Eli Duke via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Reducing emissions from cement

November 14, 2024 By EarthWise Leave a Comment

Cement production accounts for about 7% of global carbon emissions. It is one of the most difficult challenges for emissions reduction. The emissions associated with producing cement come from both the energy used to provide heat for the process and from the chemical reactions that take place in the formation of cement. Cement is an essential building block of society, and its use is not expected to decline over time.

A German company called Heidelberg Materials is embarking on an ambitious project to reduce carbon emissions from a cement plant in Norway. They are building a facility to use absorbent chemicals to capture large quantities of carbon dioxide emitted through cement production. More than half a ton of carbon dioxide arises from every ton of cement produced at the plant.

Once the carbon dioxide is captured it will be chilled to a liquid, loaded onto ships, and carried to a terminal farther up the Norwegian coast. From there, it will be pumped into undersea rocks located 70 miles offshore and a mile and a half below the bottom of the North Sea.

With all of this complicated process going on, cement from the plant is likely to be quite expensive. It might even be two or three times the price of ordinary cement. Heidelberg Materials is counting on customers’ willingness to pay much more for cement that comes with green credentials.

Can this be economically viable? Heidelberg estimates that cement accounts for only about 2% of the cost of a large building project but as much as 50% of the emissions. As a result, using carbon-free cement could be a relatively inexpensive way for builders to reduce emissions.

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Cement Is a Big Polluter. A Plant in Norway Hopes to Clean It Up.

Photo, posted May 7, 2016, courtesy of Phillip Pessar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

An electric reactor for industry

September 17, 2024 By EarthWise Leave a Comment

The industrial sector accounts for nearly a third of greenhouse gas emissions in the US, which is more than the annual emissions from cars, trucks, and airplanes combined. These emissions primarily come from burning fossil fuels to produce goods from raw materials as well as from the chemical reactions associated with production. Many industrial processes require very high temperatures that are not easily achieved other than by burning fossil fuels.

Researchers at Stanford University have developed and demonstrated a new kind of thermochemical reactor that can generate the huge amounts of heat required for many industrial processes that runs on electricity rather than the burning of fossil fuels. The researchers claim that the design is also smaller, cheaper, and more efficient than the fossil fuel technology it would replace.

Standard industrial thermochemical reactors burn fossil fuel to heat a fluid that is piped into the reactor, much like the way home radiators work, albeit at far higher temperatures. The new reactor uses magnetic induction, similar to the way that induction cooktops work. Heat is transferred by inducing a current into materials that heat up as the current flows.

A proof-of-concept demonstration powered a chemical reaction called the reverse water gas shift reaction and resulted in more than 85% efficiency. The reaction in question converts carbon dioxide into a valuable gas that can be used to create sustainable fuels.

The Stanford researchers are working to scale up their new reactor technology and expand its potential applications. They are working on designs for reactors for capturing carbon dioxide and for manufacturing cement.

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Electric reactor could cut industrial emissions

Photo, posted October 30, 2022, courtesy of Helmut via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Concrete And Carbon | Earth Wise

May 8, 2023 By EarthWise Leave a Comment

After water, concrete is the world’s second most consumed material. It is the cornerstone of modern infrastructure. Its production accounts for 8% of global carbon dioxide emissions. The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement. These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat. However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide. The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete. The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly. Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint. In addition, the resulting concrete sets much more quickly. It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Carbon Into Stone | Earth Wise

January 31, 2023 By EarthWise Leave a Comment

A start-up company in Oman called 44.01 was recently awarded a $1.2 million Earthshot Prize by Prince William of the U.K. The company, whose name corresponds to the molecular weight of carbon dioxide, is working on speeding up natural chemical reactions that take carbon from the air and lock it into solid mineral form.

The company’s location in Oman is no random occurrence. The mountains of northern Oman and along the coast of the United Arab Emirates are the site of a huge block of oceanic crust and upper mantle that was thrust upward some 96 million years ago. The tilted mass of rock is over 200 miles long and is the largest surface exposure of the Earth’s mantle in the world.

This type of rock, called peridotite, is rich in olivine and pyroxene, which react with water and carbon dioxide to form calcium-based minerals like serpentine and calcite that permanently lock in carbon. Other kinds of rock also are capable of carbon-storing mineralization, but this mantle rock is the most effective for the purpose. It only exists at the Earth’s surface in a few places, including Papua New Guinea and some spots in California and Oregon.

The 44.1 company is planning to use solar-powered direct air capture devices to remove CO₂ from the air, use it to produce carbonated water, and inject the water into the reactive rocks. The company will operate a couple of pilot systems during 2023. Ultimately, the company believes it can scale up the process to be able to permanently sequester as much as a billion tons of CO₂ a year by the year 2040 without needing to inject the gas into deep caverns or find other places to store it.

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With Major Prize, a Project to Turn Carbon Emissions to Stone Gains Momentum

Photo, posted August 10, 2018, courtesy of JM McBeth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

July 19, 2022 By EarthWise Leave a Comment

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The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications. Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt.

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly. However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages. The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers. Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes. This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese. It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.