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chemical compounds

Protecting wine grapes from wildfire smoke

February 27, 2024 By EarthWise Leave a Comment

In recent years, wildfires have become a major threat to the wine industry because of the effects of smoke on wine grapes.  Smoke taint from the California fires of September 2020 significantly impacted the quality of wine grapes.  In total, smoke taint cost the wine industry in Western states more than $3 billion in losses from the hundreds of thousands of tons of wine grapes that could not be harvested because of the off flavors imparted by the smoke.  The California wine industry alone is a $43 billion a year business and the state’s frequent wildfires are a major threat to it.

Researchers at Oregon State University have developed techniques for eliminating the effects of three volatile chemical compounds that contribute to smoke taint in grapes.  The compounds are guaicol, syringol, and meta-cresol.

The researchers developed cellulose nanofiber-based coatings that can be applied to grapes in the vineyard.  The coatings can block guaicol and syringol and capture meta-cresol.

Blocking is ideal because the coating doesn’t absorb the wildfire smoke compounds.  Therefore, it doesn’t have to be washed off.  Capturing means the coating absorbs the compounds and would need to be washed off.  Ideally, a coating that doesn’t need to be washed off would save time, money, and water.

Two years of studies at Oregon State found that the coatings do not impact the growth and quality of wine grapes.  In an era when wildfires are increasingly common and extensive, growers need something they can spray on their vines to protect their grapes.  If the Oregon State technology can be commercialized, it would be a game-changer for the Western U.S. wine industry.

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Spray coating for grapes shows promise in battle between wildfire smoke and wine

Photo, posted October 3, 2006, courtesy of Naotake Murayama via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Sunscreen And Coral Reefs | Earth Wise

May 18, 2021 By EarthWise Leave a Comment

Toxic sunscreens are killing corals

The dangers of overexposure to UV solar radiation have led to the extensive production and use of sunscreen products.  It is generally understood that many of the chemical compounds used in sunscreen products have toxic effects on marine organisms, but research in this area is relatively limited.

There are estimates that as many as 82,000 kinds of chemicals from personal care products have made their way into the world’s oceans.  In 2015, it was estimated that around 14,000 tons of sunscreen are ending up in the world’s coral reefs per year and causing irreparable damage.

Eighty-five percent of the Caribbean’s coral reefs died before the turn of the century, not as a result of global warming, but because of pollution.  Oxybenzone and octinoxate are two of the common sunscreen ingredients that are most toxic to corals.  Preservatives like parabens are also toxic.

There are much safer sunscreens such as those based on zinc oxide or titanium oxide.  In some places, such eco-friendly sunscreens are mandatory.  Sunscreens with SPF values above 30 contain a higher percentage of chemicals and have been shown to not really provide any more protection than SPF 30 products.

Apart from the choice of sunscreen product, if one really wants to reduce the negative impact sunscreen has on reefs and marine life, wearing sun-protective clothing such as rash-guards will allow the use of much less sunscreen and therefore result in less of it entering the ocean.

Products that can help protect against the harmful effects of UV radiation on human health are extremely important, but it is also important to identify and quantify the risks associated with these products to reef ecosystems.

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How to Know If Your Sunscreen Is Killing Coral Reefs — and the Brands to Try Instead

Impacts of sunscreen on coral reefs needs urgent attention, say scientists

Photo, posted January 11, 2015, courtesy of Elch Korallen via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plants Paying For Biofuels | Earth Wise

May 7, 2020 By EarthWise Leave a Comment

Plants can make biofuels cheaper

Biofuels are an important element in broader strategies to replace petroleum in transportation fuels like gasoline, diesel, and jet fuel.  The idea is that biofuels recycle carbon by getting it from growing plants rather than from fossil sources.  The biggest problem with biofuels is that they cost more than conventional petroleum fuels, so there is economic incentive to keep burning the fossil fuels.

One strategy to make biofuels cost competitive is to have the plants provide additional economic benefits beyond being a feedstock for fuel.  This in principle can be done by engineering plants to produce valuable chemical compounds, or bioproducts, as they grow.  Bioproducts include such things as flavoring agents and fragrances as well as biodegradable plastic.  These bioproducts can be extracted from the plants and then the remaining plant material can be converted to fuel. 

Researchers at Lawrence Berkeley National Laboratory recently published a study to determine what quantities of bioproducts plants need to produce to result in cost-effective biofuel production.

The study looked at a compound called limonene, which is used for flavoring and fragrance.  They calculated that if this compound was accumulated at 0.6% of the biomass dry weight, it would offer net economic benefits to biorefineries.  This corresponds to recovering 130 pounds of limonene from 10 tons of sorghum on an acre of land.

Such quantities are completely practical but, on the other hand, none of these substances are needed in huge quantities. Just six refineries could supply the world with limonene.  So, fuel crops would need to be engineered to produce a broad range of bioproducts to enable a viable cost-effective biofuel industry.

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Making Biofuels Cheaper by Putting Plants to Work

Photo, posted September 28, 2019, courtesy of Michele Dorsey Walfred via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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