tough

Repurposing used tires

April 29, 2025 By EarthWise Leave a Comment

Every year, millions of tires from cars and trucks end up in landfills. Just in the U.S., more than 270 million tires were scrapped in 2021 and more than 50 million of them ended up in landfills. Discarded tires take up huge amounts of space but, more importantly, create environmental hazards. They leach chemicals into the environment and are a serious fire hazard.

Some tires are chemically recycled via pyrolysis, which is a high-temperature process to decompose the materials in the tire. But that process introduces harmful byproducts like benzene and dioxins.

Researchers at the University of North Carolina Chapel Hill have introduced a new chemical method for breaking down rubber waste. The process transforms discarded rubber into valuable precursors for epoxy resins.

Rubber – either natural rubber or the synthetic kind used in tires – is made of polymers cross-linked together to form a tough, flexible, and durable material. These very desirable properties make it difficult to break down rubber.

The new research has led to a two-step chemical process that breaks down the rubber into functional materials that be used to produce epoxy resins. The method does not require extremely high temperatures, uses aqueous media, and takes only six hours. It represents an efficient, scalable solution for repurposing rubber waste which, even as many other aspects of motor vehicle are changing for the better, remains a continuing environmental problem associated with driving.

This new research marks a significant step towards greener recycling technologies.

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A Cleaner Future for Tires: Scientists Pioneer Chemical Process to Repurpose Rubber Waste

Photo, posted May 5, 2011, courtesy of TireZoo via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic from food waste

April 9, 2025 By EarthWise Leave a Comment

Plastic waste management is a complicated business. Most methods of recycling or breaking down plastic are costly and harmful to the environment. The most common biodegradable alternatives – like paper straws – are less than ideal replacements.

There are many approaches to creating biodegradable plastics using feedstocks like seaweed, sugarcane, and other plant matter. However, the resulting plastics often fall short compared with conventional petroleum-based plastics.

One type of bioplastic that is gaining popularity is polyhydroxyalkanoates, or PHA. PHA is a plastic produced by microorganisms. It is fully compostable or biodegradable but in other ways but looks, feels, and functions like regular plastic but without the environmental drawbacks.

PHA can be made using bacterial fermentation of a variety of feedstocks such as vegetable oils, sugars, starches, and even methane and wastewater.

Researchers at a startup from the University of Waterloo in Canada called MetaCycler BioInnovations have developed a process for producing PHA based on bacteria that has been engineered to convert waste from milk and cheese production. This solution upcycles waste from the dairy industry into cost-effective, sustainable bio-based plastics.

PHAs can be tailored to have a wide range of properties ranging from being rigid and tough to being quite flexible. Therefore, they can be suitable for many applications including packaging, agricultural films, and consumer goods.

The Waterloo technology is a way to tackle the problems of both food waste and plastic pollution with one solution.

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Turning food waste into a new bioplastic

Photo, posted December 10, 2017, courtesy of Leonard J Matthews via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Recycling Tough Plastics | Earth Wise

September 3, 2020 By EarthWise Leave a Comment

Thermoset plastics are ones that contain polymers that cross-link together during the curing process to form an irreversible chemical bond. This improves the material’s mechanical properties, provides chemical resistance, heat resistance, and structural integrity. Thermosets include epoxies, polyurethanes, and rubber used for tires. The big problem with thermosets is that they cannot be easily recycled or broken down after use.

Seventy-five percent of all plastics are thermoplastics, which can be recycled by heating them until they become liquid and can then be remolded. Thermoset plastics, on the other hand, have such strong chemical bonds that they simply will not melt. They will typically burn before they can be remolded.

Chemists at MIT have recently developed a way to modify thermoset plastics with a chemical linker that makes them much easier to break down, but still retain the mechanical properties that make them so useful.

In a study published in Nature, the researchers produced a degradable version of a thermoset plastic called pDCPD. They then broke the plastic down into a powder and were able to use the powder to create more pDCPD. The paper also proposed a theoretical model that suggests that their approach could be used for a wide range of other plastics and polymers, including rubber.

By adding a chemical called a silyl ether monomer to the liquid precursors that from pDCPD plastic, they found that the resultant material retained its mechanical strength but can be broken down into a soluble powder upon exposure to fluoride ions.

Using this approach with other thermoset materials, the researchers believe it will be possible to create recyclable versions of many of the toughest plastic materials.

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Chemists make tough plastics recyclable

Photo, posted September 1, 2019, courtesy of Luke McKernan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Is There Hope For Coral Reefs?

January 16, 2019 By EarthWise Leave a Comment

News about the world’s coral reefs has been relentlessly bad for a number of years. Warming, acidifying oceans have wreaked havoc with coral reefs leading to enormous losses. Nowhere have things been more dire than in Australia’s Great Barrier Reef. Coral bleaching events have been increasingly common and severe over the past two decades. In fact, only 7% of the Great Barrier Reef has escaped bleaching entirely since 1998.

While the future of the world’s coral reefs is very much uncertain as global heating continues, there is a recent bit of hopeful news. According to a study published in Nature Climate Change, the response of the Great Barrier Reef to the extreme temperatures in 2017 was quite different from that of the previous year in the aftermath of back-to-back bouts of coral bleaching.

Surprisingly, corals that bleached in 2016 but managed to survive were more resistant to the recurrence of hot conditions in 2017.

Many corals don’t survive bleaching events at all and, of course,those corals don’t bleach for a second time. But the surviving corals from the 2016 bleaching event were tougher species. As a result of bleaching, the mix of coral species on the reef is changing very rapidly. The net result was that there was less bleaching in 2017 even though the temperatures that year were even more extreme than in 2016.

There have now been four mass bleaching events on the Great Barrier Reef over the past 20 years and it is only a matter of time before another one occurs triggered by the next marine heatwave. Almost half of the corals on the northern two-thirds of the reef have been killed. But at least some of the reef is showing impressive survival skills.

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A glimmer of hope for the world’s coral reefs

Photo, posted November 29, 2012, courtesy of Robert Linsdell via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.