sodium bicarbonate

Storing Carbon Dioxide In The Ocean | Earth Wise

May 11, 2023 By EarthWise 2 Comments

Reducing the amount of carbon dioxide entering the atmosphere means either shutting down emission sources (primarily curbing the use of fossil fuels) or capturing the CO2 as it is emitted. Capturing carbon dioxide from smokestacks and other point sources with high concentrations is relatively efficient and can make economic sense. Removing it from the air, which even at today’s dangerously high levels contains only 400 parts per million, is difficult and energy intensive. And even when it is removed, it then must be stored somewhere.

Researchers at Lehigh University have developed a novel way to capture carbon dioxide from the air and store it in what is effectively the infinite sink of the ocean. The approach uses an innovative copper-containing filter that essentially converts CO2 into sodium bicarbonate (better known as baking soda.) The bicarbonate can be released harmlessly into the ocean.

This technique has produced a 300 percent increase in the amount of carbon dioxide captured compared with existing direct air capture methods. It does not require any specific level of carbon dioxide to work. The filter becomes saturated with the gas molecules as air is blown through it. Once this occurs, seawater is passed through the filter and the CO2 is converted to dissolved bicarbonate. Dumping it into the ocean has no adverse effect on the ocean. It doesn’t change the salinity at all, and the stuff is slightly alkaline, which will help reduce ocean acidification.

Reusing the filter requires cleaning it with a sodium hydroxide solution, which can be created from seawater using electricity generated by waves, wind, or sun.

The filter, called DeCarbonHIX, is attracting interest from companies based in countries around the world.

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Path to net-zero carbon capture and storage may lead to ocean

Photo, posted March 10, 2007, courtesy of Gail via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Concrete And Carbon | Earth Wise

May 8, 2023 By EarthWise Leave a Comment

After water, concrete is the world’s second most consumed material. It is the cornerstone of modern infrastructure. Its production accounts for 8% of global carbon dioxide emissions. The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement. These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat. However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide. The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete. The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly. Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint. In addition, the resulting concrete sets much more quickly. It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Self-Deicing Roads | Earth Wise

March 23, 2023 By EarthWise Leave a Comment

Driving on snowy or icy roads can be pretty dangerous. That is why roads are salted or coated with sand to provide traction in icy weather. But excessive use of these substances is bad for the environment and sometimes a storm will blow in before the roads can be coated.

In a paper published in the American Chemical Society Journal ACS Omega, researchers in China describe a method of adding microcapsules filled with a chloride-free salt mixture to the asphalt with which roads are paved. The idea is to provide the road itself with long-term snow melting capabilities.

The researchers prepared a sodium-acetate salt and combined it with a surfactant, silicon dioxide, sodium bicarbonate, and blast furnace slag, which is a waste product from power plants. The substances were reduced to a fine powder and then coated with a polymer solution to form tiny microcapsules. The microcapsules were then used to replace some of the standard mineral filler in asphalt.

Lab experiments showed that the special additive lowered the freezing point of water on the asphalt to -6 degrees Fahrenheit. The researchers estimated that a 2-inch-thick layer of the anti-icing asphalt would be effective at melting snow for seven or eight years. A real-world pilot test of the coating on a highway offramp showed that it melted snow that fell on the road whereas an uncoated road required snow removal operations.

According to the researchers, given the cost of materials used for the coating and its potential useful lifetime, it could be a practical and economic enhancement for wintertime snow and ice removal. Maybe we’ll someday have roads that can fairly often deice themselves.

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Keeping drivers safe with a road that can melt snow, ice on its own

Photo, posted April 8, 2007, courtesy of the Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio