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New Membranes For Carbon Capture

October 2, 2019 By EarthWise Leave a Comment

Drastically reducing the amount of carbon dioxide being emitted into the atmosphere is an essential goal in the effort to mitigate the effects of climate change.  While the ultimate solution is to avoid combustion of fossil fuels by the use of clean alternative energy sources, that transition will take time – possibly more time than we have.  As a result, there is a great deal of effort underway to develop techniques for capturing the carbon emitted by fossil fuel combustion and either recycling it or storing it.

There are multiple ways to capture carbon emissions, but the ultimate goal is to find a technique that is both inexpensive and scalable.  One promising technique involves the use of high-performance membranes, which are filters that can specifically pick out CO2 from a mix of gases, such as those coming out of a factory smokestack.

Scientists at a Swiss laboratory have now developed a new class of high-performance membranes that exceeds the targeted performance for carbon capture by a significant margin.  The membranes are based on single-layer graphene with a selective layer thinner than 20 nanometers – only about 40 atoms thick. The membranes are highly tunable in terms of chemistry, meaning that they can be designed to capture specific molecules.

The membranes are highly permeable – meaning that they don’t impede gas flow too much – but highly selective.  The CO2/N2 separation factor is 22.5, which means that 22.5 times more nitrogen can get through the membrane than carbon dioxide.

The work is just at the laboratory stage at this point, but it is a very promising step towards developing a practical scheme for keeping carbon dioxide from escaping from power-plant and factory smokestacks.

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Next-gen membranes for carbon capture

Photo, posted December 28, 2010, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hacking Photosynthesis

February 25, 2019 By EarthWise Leave a Comment

There is an enzyme known as RuBisCo that is involved in carbon fixation, the process plants use to convert carbon dioxide into sugar molecules.  The RuBisCo molecule is inside the leaves of most plants and is probably the most abundant protein in the world.

RuBisCo picks up carbon dioxide from the air and uses energy from the sun to turn the carbon into sugar molecules.  This process of photosynthesis is pretty much the foundation of life on Earth.

Wonderful as it is, the process is not perfect.  RuBisCo is not very selective in grabbing molecules from the air.  It picks up oxygen as well as CO2 and it produces a toxic compound when it does that.

Plants operate a whole other complicated chemical process to deal with this toxic byproduct and uses up a lot of energy along the way, leaving less energy for making leaves or food that we can eat.

A research program at the University of Illinois called Realizing Increased Photosynthetic Efficiency (or RIPE) has been trying to correct this problem; they have been trying to hack photosynthesis.  And they may well have succeeded.

Using genetic modification on tobacco plants, they have shut down the existing detoxification process and set up a much more efficient new one.  The result is super plants that grow faster and up to 40% bigger.

The next step is to get it to work on plants that people actually rely upon for food, like tomatoes, soybeans and black-eyed peas (which are a staple food crop in sub-Saharan Africa where food is scarce.)

It will be years before we know if the process can really produce more food and be safe, but it may end up leading to a major increase in crop productivity.

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Scientists Have ‘Hacked Photosynthesis’ In Search Of More Productive Crops

Photo, posted June 10, 2013, courtesy of Boon Hong Seto via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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