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Reducing emissions from ocean shipping

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Ocean shipping is a significant contributor to global carbon emissions, accounting for about 3% of the total.  It is a key part of international trade, moving goods like electronics, automobiles, and oil.  It relies on fossil fuels, and, without significant changes, shipping’s emissions could more than double by 2050.  Ocean shipping is one of the world’s most difficult to decarbonize industrial sectors.

Scientists at the University of Southern California and Caltech, collaborating with a startup company called Calcarea, have developed a shipboard system that could remove up to half of the carbon dioxide emitted by shipping vessels. The system is fairly simple and scalable.

The process mimics a natural chemical reaction that takes place in the ocean.  As a cargo ship moves through seawater, the CO2 from the ship’s exhaust is absorbed into water that is pumped onboard.  This makes the water more acidic.  The treated water is then passed through a bed of limestone, where it reacts with the rock to form bicarbonate, which is a stable compound that already exists naturally in seawater.  The treated seawater, now stripped of the carbon dioxide, is dumped back into the ocean.

Sophisticated ocean modeling examined what would happen when the bicarbonate-rich water is released back into the sea over a hypothetical 10-year period.  The model showed a negligible impact on ocean pH and chemistry.

The researchers estimate that widespread adoption of the technique could reduce shipping-related carbon dioxide emissions by 50%.  The startup company Calcarea is working to bring the technology to market and is in early discussions with commercial shippers.

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USC technology may reduce shipping emissions by half

Photo, posted November 14, 2017, courtesy of Bernard Spragg via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Repurposing used tires

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Every year, millions of tires from cars and trucks end up in landfills.  Just in the U.S., more than 270 million tires were scrapped in 2021 and more than 50 million of them ended up in landfills.  Discarded tires take up huge amounts of space but, more importantly, create environmental hazards.  They leach chemicals into the environment and are a serious fire hazard.

Some tires are chemically recycled via pyrolysis, which is a high-temperature process to decompose the materials in the tire.  But that process introduces harmful byproducts like benzene and dioxins. 

Researchers at the University of North Carolina Chapel Hill have introduced a new chemical method for breaking down rubber waste.  The process transforms discarded rubber into valuable precursors for epoxy resins.

Rubber – either natural rubber or the synthetic kind used in tires – is made of polymers cross-linked together to form a tough, flexible, and durable material.  These very desirable properties make it difficult to break down rubber.

The new research has led to a two-step chemical process that breaks down the rubber into functional materials that be used to produce epoxy resins.  The method does not require extremely high temperatures, uses aqueous media, and takes only six hours.   It represents an efficient, scalable solution for repurposing rubber waste which, even as many other aspects of motor vehicle are changing for the better, remains a continuing environmental problem associated with driving.

This new research marks a significant step towards greener recycling technologies.

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A Cleaner Future for Tires: Scientists Pioneer Chemical Process to Repurpose Rubber Waste

Photo, posted May 5, 2011, courtesy of TireZoo via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fighting fires with man-made wind

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Researchers at Ohio State University have developed a new portable tool that may help firefighters battle blazes more efficiently and with less risk.

Traditional firefighting methods include chemical foams – which are toxic – and the use of hydrants, which can strain water resources.  The recent fires in Southern California demonstrated the need for efficient fire suppression methods.  The new device works to suppress flames using conductive aerosols, which are small particles that can direct electricity.

The device uses vortex rings – small donut-shaped bands of air – that transform the aerosol particles into short pulses of wind that convert nearby oxygen into ozone.  This accelerated airflow generates rapid turbulence, which disrupts the natural combustion process and quickly extinguishes the target fire.

The device resembles a small bucket, attached to an arm brace.  Firefighters would aim the bucket toward the fire, and it would use bursts of compressed air to deliver aerosols in an electric arc to fight the fire.

Testing identified a coarse copper solution for the vortex ring material and simulations showed that the device would succeed in suppressing fires.  They then worked on optimizing the power and range of the device.

Depending on the size of the fire and number of firefighters, it is likely that several of the devices would be required in a real emergency.  According to the developers, the design of the vortex launcher is actually very simple and is very scalable.  The device is maneuverable in tight spaces and could be taken through doors and indoor environments.  Vortex rings can carry chemical payloads over longer distances than other methods, making firefighters safe by staying further from flames. 

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New device uses electrically assisted wind to fight fires

Photo, posted November 12, 2024, courtesy of the USDA Forest Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Protecting Bees From Pesticides | Earth Wise

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Studies have shown that the wax and pollen in 98% of beehives in the U.S. are contaminated with an average of six pesticides.  These substances lower bees’ immunity to devastating varroa mites and other pathogens.  By some estimates, pesticides cause beekeepers to lose about a third of their hives every year on average.

Researchers at Cornell University have developed a new technology that effectively protects bees from insecticides.  The insecticide antidote delivery method is now the basis of a new company called Beemunity.

The Cornell researchers developed a uniform pollen-sized microparticle filled with enzymes that detoxify organophosphate insecticides before they are absorbed and can harm bees.  Organophosphate insecticides account for about a third of the insecticides on the market.  The microparticles have a protective casing that allows the enzymes to move past the bees’ crop (basically the stomach), which is acidic and would otherwise break them down.  The safeguarded enzymes then enter the midgut, where digestion occurs and where toxins and nutrients are absorbed.  There the enzymes act to break down and detoxify the organophosphate insecticides.

In experimental tests, bees that were fed the enzyme-filled microparticles had a 100% survival rate after exposure to the insecticide malathion.  Unprotected control bees died within days.

The Cornell work appears to represent a low-cost, scalable solution to the insecticide toxicity issue and may help to protect essential pollinators.

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Pollen-sized technology protects bees from deadly insecticides

Photo, posted January 30, 2020, courtesy of George Tan via Flick.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Membrane For Converting Carbon Dioxide | Earth Wise

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Methanol is a valuable chemical used as fuel in the production of countless products. Carbon dioxide is a greenhouse gas that is produced by countless industrial processes.  Carbon dioxide can be converted into methanol, which is one way all that CO2 can be put to good use instead of causing harm. 

In research recently published in Science, chemical engineers from Rensselaer Polytechnic Institute have developed a process that converts CO2 to methanol in a more efficient way by using a highly effective separation membrane they produced.  

The chemical reaction responsible for the transformation of CO2 into methanol also produces water, which severely restricts the continued reaction. The Rensselaer team has found a way to filter out the water as the reaction is happening, without losing other essential gas molecules. 

They produced a membrane made up of sodium ions and zeolite crystals that was able to carefully and quickly permeate water through small pores — known as water-conduction nanochannels — without losing gas molecules. The sodium ions effectively only allow water to go through. When water was effectively removed from the process, the team found that the chemical reaction was able to happen very quickly. By removing the water, the equilibrium shifts, which means more CO2 will be converted and more methanol will be produced.  

The team is now working to develop a scalable process and a startup company that would allow this membrane to be used commercially to produce high purity methanol.  This membrane could also be used to improve a number of other reactions. 

In industry there are many reactions limited by water and this RPI membrane could be an important enhancement for many of them. 

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Water-Conducting Membrane Allows Carbon Dioxide To Transform into Fuel More Efficiently

Photo courtesy of RPI.

Earth Wise is a production of WAMC Northeast Public Radio.

Emissions-Free Cement

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The production of cement – which is the world’s leading construction material – is a major source of greenhouse gas emissions, accounting for about 8% of global man-made emissions. 

Cement production produces carbon dioxide in two ways:  from a key chemical process and from burning fuel to produce the cement.  The process of making “clinker” – the key constituent of cement – emits the largest amount of CO2.  Raw materials, mainly limestone and clay – are fed into huge kilns and heated to over 2,500 degrees Fahrenheit, requiring lots of fossil fuel.  This calcination process splits the material into calcium oxide and CO2.  The so-called clinker is then mixed with gypsum and limestone to produce cement.

A team of researchers at MIT has come up with a new way of manufacturing cement that greatly reduces the carbon emissions.  The new process makes use of an electrolyzer, where a battery is hooked up to two electrodes in water producing oxygen at one electrode and hydrogen at the other.  The oxygen-evolving electrode produces acid and the hydrogen-evolving electrode produces a base.  In the new process, pulverized limestone is dissolved in the acid at one electrode and calcium hydroxide precipitates out as a solid at the other.

High-purity carbon dioxide is released at the acid electrode, but it can be easily captured for further use such as the production of liquid fuels or even in carbonated beverages and dry ice.  The new approach could eliminate the use of fossil fuels in the heating process, substituting electricity generated from renewable sources. 

The process looks to be scalable and represents a possible approach to greatly reducing one of the perhaps lesser known but nevertheless very significant sources of greenhouse gas emissions.

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New approach suggests path to emissions-free cement

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Spider Silk

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Spider silk – the protein fiber spun by spiders to make webs, nests, cocoons, and wrapping for prey that they stash away – is a remarkable substance.  Its mechanical properties combine high tensile strength and high extensibility or ductility.  This allows spider silk to absorb a lot of energy before breaking.   It is stronger than steel, but not as strong as Kevlar, for example.  On the other hand, it is tougher than either.

[Read more…] about Spider Silk

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