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organic compounds

Tracking down PFAS toxins

December 5, 2023 By EarthWise Leave a Comment

PFAS – per- and polyfluoralkyl substances – are a group of organic compounds that have been extensively used to provide water-, oil-, and dirt-resistance to a wide range of products ranging from non-stick pans, clothing, and packaging to paint, car polish, and fire-suppressant foam.  Exposure to specific PFAS compounds is associated with multiple adverse health effects, including altered immune and thyroid function, liver disease, kidney disease, poor reproductive and developmental outcomes, and cancer.  PFAS compounds do not break down in the environment and therefore, over time, become concentrated in plants, animals, and people.

Government agencies such as the EPA in this country and the EU have set strict limits for allowable levels of PFAS in drinking water.  Testing water for the trace amounts of PFAS that constitute the limits is time-consuming and expensive and requires complex equipment and experienced personnel.

Researchers at MIT have now introduced a technique for making a portable, inexpensive test that can easily and selectively detect PFAS in water samples.  The test makes use of a special polymer containing fluorinated dye molecules that cause the polymer to fluoresce red.  If PFAS are present in the sample, they enter the polymer and displace the dye molecules and switches off the red fluorescence. 

The new technique is suitable for on-site detection in highly contaminated regions.  Detecting smaller concentrations can be achieved with sufficient precision after pre-concentrating the samples using the process of solid-phase extraction.

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Tracking down Environmental Toxins

Photo, posted October 16, 2021, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic From Sunlight | Earth Wise

March 13, 2023 By EarthWise Leave a Comment

Photosynthesis is the process that plants use to turn water, carbon dioxide, and energy from sunlight into plant biomass.  It provides humans and much of animal life with food.  Photosynthesis is also nature’s way of reducing the amount of carbon dioxide in the atmosphere.  The CO2 is not directly stored in plants but rather is combined into organic compounds.

Researchers across the globe are trying to find effective ways to mimic photosynthesis.  One version of artificial photosynthesis seeks to take carbon dioxide and combine it into organic compounds that can be used as raw materials for various kinds of manufacturing. 

A research team in Japan has found a way to synthesize fumaric acid from carbon dioxide using sunlight to power the process.  Fumaric acid is a chemical typically synthesized from petroleum and is used as a raw material for making biodegradable plastics such as polybutylene succinate. 

Much of artificial photosynthesis research is aimed at using solar energy to convert carbon dioxide directly into a fuel rather than a raw material.  Such solar fuels can be produced by a variety of means including thermochemical (using the sun’s heat to drive chemical reactions), photochemical (using the sun’s light to drive chemical reactions), and electrochemical (using solar-generated electricity to drive chemical reactions.)   These approaches generally involve the use of specialized catalysts to drive the desired chemical reactions. 

One way or another, what techniques for artificial photosynthesis have in common is trying to imitate what plant life on Earth has been doing for millions of years. 

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Artificial photosynthesis uses sunlight to make biodegradable plastic

Photo, posted June 14, 2017, courtesy of Alex Holyake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

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