mysterious

Action on the toxic chemical from tires

December 13, 2023 By EarthWise Leave a Comment

Since the 1990s, populations of coho salmon in streams and urban creeks up and down the West Coast have been dying in large numbers. Scientists at the University of Washington began studying the mysterious deaths and it took years to figure out what was going on. They analyzed water samples from urban creeks and found that chemicals from vehicle tires were present. By soaking tires in water, they found that more than 2,000 chemicals were present. It took three years to narrow down the suspect list to one chemical: a toxin called 6PPD-quinone, which is produced when the common tire preservative 6PPD mixes with oxygen. It is that chemical that was responsible for the salmon die-off.

6PPD-quinone is toxic enough to quickly kill some fish. Studies showed that concentrations of the chemical in stormwater were found to be lethal for coho salmon following exposures lasting only a few hours.

Despite the discovery, the tire industry has continued to use the chemical in its products. The industry says 6PPD is an antioxidant and antiozonant that helps prevent degradation and cracking of tires in the environment and is essential for the performance and safety of vehicles.

Last year, California regulators directed the tire industry to seek out substitutes for 6PPD. The U.S. Tire Manufacturers Association pledged to investigate possible safer alternatives to the chemical.

In November, spurred by a petition by West Coast tribes whose lifeways depend on coho salmon, the EPA said it will study the impact of 6PPD with an eye to potentially banning its use.

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After Salmon Deaths, EPA Takes Aim at Toxic Chemical Issuing from Car Tires

Photo, posted May 31, 2021, courtesy of Chris Yarzab via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

What’s Been Killing Salmon? | Earth Wise

January 5, 2021 By EarthWise Leave a Comment

For decades, there have been mysterious deaths of Coho salmon. The salmon return from the Pacific Ocean each year to spawn along the West Coast. They can be found from Alaska all the way down into California. After heavy rain events each fall, fish have been turning up dead in huge numbers before they spawn. Normally, less than 1% of adult Coho die before spawning. In these mass death events, anywhere from 40% to 90% of fish can perish in affected streams. The mysterious phenomenon has been the subject of intense research for years.

Recently, scientists announced that they may have solved the mystery. There is a chemical antioxidant known as 6PPD that is used in the manufacture of tires around the world to make them last longer. As tire treads break down over time, they leave behind bits of microplastics on roads. The 6PPD in the plastic bits reacts with ozone to become another chemical: a previously unreported substance called 6PPD-quinone.

That chemical turns out to be toxic to Coho salmon. Researchers have found the presence of 6PPD-quinone in roadway water runoff samples taken from across the West Coast. Based on these observations, they believe it is likely that exposure to this chemical is the main cause of the Coho salmon population decline.

Coho salmon are a favorite of sport fishermen and have great cultural significance to many Native American tribes on the West Coast. The central California Coho population is classified as endangered and three other Coho populations are listed as threatened.

Tire industry representatives call the study results “preliminary” but say the industry is deeply committed to protecting the environment. A safe chemical substitute for 6PPD is clearly needed.

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Salmon have been dying mysteriously on the West Coast for years. Scientists think a chemical in tires may be responsible

Photo, posted November 17, 2011, courtesy of Lynn Ketchum/Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Frogs Are In Big Trouble

May 22, 2019 By EarthWise Leave a Comment

Scientists first noticed in the 1970s that some frog populations were declining rapidly. By the 1980s, some species appeared to be extinct. The loss of frog species was mysterious because many were actually living in pristine habitats that did not face pollution or deforestation.

By the late 1990s, researchers had identified that frogs in widely different places around the world were infected with a deadly fungus called Batrachochytrium dendrobatidis – or Bd for short. The fungus originated on the Korean peninsula, but the pathogen spread throughout the world, probably via the international trade in pet amphibians. By 2007, researchers speculated that Bd might be responsible for all known declines of frogs that had no other apparent cause – about 200 species.

Recently, a group of 41 scientists published the first worldwide analysis of the fungal outbreak and the devastation turns out to be far worse than anyone had previously realized. Populations of more than 500 species of amphibians have declined significantly because of the outbreak, including at least 90 species presumed to have gone extinct. These figures are more than twice as large as earlier estimates.

According to biologists, Bd is now considered to be the deadliest pathogen known to science. But the decimation of frogs peaked in the 1980s. Today, although 39% of the species that suffered population declines in the past are still declining, 12% are showing signs of recovery, possibly because natural selection is favoring resistant animals.

There is cautious optimism for the surviving amphibian species, but scientists worry that another strain of Bd or some different species of fungus altogether may prove even deadlier. The best we can do is not participate in moving pathogens around the world.

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The Plague Killing Frogs Everywhere Is Far Worse Than Scientists Thought

Photo, posted June 19, 2010, courtesy of Chris Luczkow via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.