game changer

A better way to extract lithium

December 10, 2024 By EarthWise Leave a Comment

Lithium is the critical component in the batteries that power phones and computers, electric cars, and the systems that store energy generated by solar and wind farms. Lithium is not particularly rare, but it is difficult and often environmentally harmful to extract from where it is found.

Traditional ore sources are increasingly difficult and expensive to mine. The largest known deposits of lithium are in natural brines – the salty water found in geothermal environments. These brines also contain other ions like sodium, potassium, magnesium, and calcium, and efficiently separating out the lithium is extremely challenging.

Traditional separation techniques consume large amounts of energy and produce chemical waste, particularly hazardous chlorine gas. These techniques typically suffer from poor selectivity; that is, the process is interfered with by the other ions present in natural brines.

A team of researchers at Rice University has developed a three-chamber electrochemical reactor that improves the selectivity and efficiency of lithium extraction from brines. The middle chamber of the reactor contains a specialized membrane that acts as a barrier to chloride ions, preventing them from getting to the electrode area where they can form chlorine gas.

The new reactor has achieved a lithium purity rate of 97.5%, which means the setup can effectively separate lithium from other ions in the brine and allow the production of high-quality lithium hydroxide, the key material for battery manufacturing.

The Rice University reactor design has the potential to be a game changer for lithium extraction from geothermal brines.

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‘Game changer’ in lithium extraction: Rice researchers develop novel electrochemical reactor

Photo, posted October 21, 2023, courtesy of Simaron via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Better Plastic Recycling | Earth Wise

September 14, 2023 By EarthWise Leave a Comment

Many of us are careful to put our plastic trash into the appropriate recycling bins hoping that we are helping to stem the global tide of plastic waste. But many plastics are not recyclable at all and recycling those that are is not even always a good thing. Breaking down plastics can generate polluting microplastics that are themselves a major environmental problem. And perhaps the biggest problem for recycling efforts is that they are not cost effective and generally incur huge losses.

Chemical engineers at the University of Wisconsin-Madison recently published a study in the journal Nature outlining a new technique for turning low-value waste plastic into high-value industrial chemicals.

The technique makes use of two existing chemical processing techniques. The first is pyrolysis, which is high-temperature heating in an oxygen-free environment. Heating waste plastic in this way produces pyrolysis oil, a liquid mix of various compounds that includes large amounts of olefins. Olefins are simple hydrocarbons that are a central building block of many chemicals and polymers. Olefins are most often produced by energy-intensive processes like steam cracking of petroleum.

The UW-Madison process takes the olefins and subjects them to a process called homogenous hydroformylation catalysis, which converts them into aldehydes, which can then be further reduced into important industrial chemicals.

The payoff is that the process can take waste plastics, which are only worth about $100 a ton, and turn them into high-value chemicals worth $1,200-$6,000 a ton. If the process can be optimized and otherwise made ready for industrial-scale use, it would be a real game-changer in the battle against plastic waste.

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New recycling process could find markets for ‘junk’ plastic waste

Photo, posted September 16, 2015, courtesy of Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A New Way To Remove CO2 From The Air

December 13, 2019 By EarthWise Leave a Comment

Researchers at MIT have developed a new way of removing carbon dioxide from a stream of air that could be a powerful tool in the battle against climate change. The new system can pull carbon dioxide out of almost any concentration level of the gas, even including the roughly 400 parts per million level currently found in the atmosphere.

The technique is described in a new paper in the journal Energy and Environmental Science and is based on passing air through a stack of electrochemical plates. The device is essentially a large battery that absorbs carbon dioxide from the air passing over its electrodes as it is being charged up, and then releases the gas as it is being discharged.

To use it, the device would simply alternate between charging and discharging. Fresh air or some other feed gas would be blown through the system during the charging cycle and then pure, concentrated carbon dioxide would be blown out during discharging.

The specialized battery uses electrodes coated with a compound called polyanthraquinone, which is composited with carbon nanotubes. These unique electrodes have a binary affinity to carbon dioxide, which means that they either strongly want to capture carbon dioxide or not at all, depending upon whether the device is charging or discharging.

Carbon dioxide is important in many industries such as soft drinks and greenhouse agriculture. With this device, the stuff could literally be pulled out of the air. And, of course, in power plants where exhaust gas is dumped into the air, these novel electrochemical cells could be used to prevent the emission of CO2 into the atmosphere. At the right price, this could be a game changer.

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MIT engineers develop a new way to remove carbon dioxide from air

Photo, posted August 9, 2007, courtesy of William Clifford via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.