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flammability

Sodium-ion batteries

January 31, 2024 By EarthWise Leave a Comment

The transition away from fossil fuels is driving a rapidly increasing need for batteries.  Both electric vehicles and energy storage for the electric grid are enormous consumers of batteries.  At present, lithium-ion batteries are almost universally used for these purposes.  They have been getting better all the time and cheaper all the time and are likely to be the answer for the foreseeable future.  But they are not perfect.

Lithium is only found in a relatively small number of places and mining and extracting it is fairly expensive and environmentally unfriendly.  Lithium-ion batteries also frequently contain cobalt, which has its own set of problems.  There are also safety issues related to the flammability of lithium-ion batteries. 

As a result, there continue to be numerous efforts to identify and develop alternative battery technologies.  One of these is sodium-ion batteries, which are similar in many ways to lithium-ion batteries but in which sodium replaces lithium as the cathode material.

Sodium is extremely common – it’s found in ordinary salt – and sodium-ion batteries have a high energy density and are easy to produce.  They should have a long lifetime and have a more benign environmental impact than lithium-ion.  Many companies and researchers are working on sodium-ion batteries and are making good progress.

A study by Chalmers University in Sweden looked at the potential for sodium-ion batteries and found that the batteries are particularly promising for use in energy storage even in their current state of development and could eventually be used in cars.  Whether sodium-ion batteries can be good enough and cheap enough quickly enough to give lithium-ion a run for its money remains to be seen.

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Resource-efficient and climate-friendly with sodium-ion batteries

Photo, posted March 12, 2013, courtesy of Chris Hunkeler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Better Zinc Batteries | Earth Wise

May 17, 2023 By EarthWise Leave a Comment

The rapid growth of wind and solar power continues to drive a global quest for new battery technologies that can be used to store the energy generated by these sources when the sun isn’t shining, and the wind isn’t blowing.

For the most part, current battery energy storage systems use lithium-ion batteries – the same sort of batteries found in cellphones and electric vehicles.  There are many other battery chemistries, but they mostly have shortcomings in performance, economy, or longevity. 

Batteries store electricity in the form of chemical energy and chemical reactions convert that energy into electrical energy. Every battery has two electrodes:  the anode, from which electrons flow into external circuits, and the cathode, which receives electrons from the external circuit.  The electrolyte is the chemical medium through which the electrons flow.

One technology that has great potential is zinc-based batteries.  Zinc itself is a metal that is safe and abundant.  Batteries based on it are energy dense. However, zinc batteries have faced the challenge of having a short cycle life.  The batteries end up plating zinc on their anodes and battery performance degrades. 

A team of researchers at Oregon State University and three other universities have recently developed a new electrolyte for zinc batteries that raises the efficiency of the zinc metal anode to nearly 100% – actually slightly better than lithium-ion batteries.

Zinc batteries have a number of potential advantages over lithium-ion.  The new hybrid electrolyte developed by the researchers is non-flammable, cost-effective, and has low environmental impact.  Lithium-ion batteries rely on the supplies of relatively rare metals that are often difficult and environmentally harmful to obtain. 

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Researchers develop electrolyte enabling high efficiency of safe, sustainable zinc batteries

Photo, posted May 13, 2017, courtesy of Jeanne Menjoulet via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

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