cracking

Seashells inspire better concrete

July 10, 2024 By EarthWise Leave a Comment

Mother of pearl – also known as nacre – is a natural material found in certain seashells such as those of oysters and abalone. On the microscopic level, it consists of hexagonal tablets of the hard mineral aragonite glued together by a soft biopolymer. The aragonite gives nacre its strength, and the biopolymer adds flexibility and crack resistance.

Scientists at Princeton University have developed innovative composite materials inspired by nacre by utilizing conventional construction materials like Portland cement paste combined with a limited amount of polymer. The new material consists of alternating layers of cement paste sheets with the highly stretchable polymer polyvinyl siloxane.

The materials were subjected to bending tests to evaluate crack resistance or fracture toughness. Three different versions of the material were tested that used different ways of interposing the polymer layers. The new materials were compared with similar structures composed entirely of cement.

The concrete-only samples were brittle, breaking suddenly and completely upon reaching their failure point. The samples with alternating cement and polymer layers demonstrated increased ductility and resistance to cracking.

By fully mimicking the structure of nacre – using completely separated hexagonal cement tablets – the researchers demonstrated materials with 19 times the ductility and 17 times the fracture toughness of cement while retaining nearly the same strength as solid cement samples.

Engineered materials inspired by nature could eventually help increase the durability of a wide range of brittle ceramic materials, from concrete to porcelain.

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From seashells to cement, nature inspires tougher building material

Photo, posted January 2, 2016, courtesy of Yantra via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Car tires in your salad

June 26, 2024 By EarthWise Leave a Comment

There seems to be no end to the types of pollution we have introduced into the environment. One that has only recently started to gain attention is pollution caused by vehicle tires.

Through normal wear and tear, as vehicles drive along roadways, their tires cast off countless bits of rubber. These particles can linger in the atmosphere or can be washed down sewage drains and into waterways. In the water, these particles leach compounds that are toxic to wildlife.

Tires contain various chemical additives that prevent them from cracking and degrading along with various metals and other materials added to rubber and artificial rubber. Some of these additives are acutely toxic or even carcinogenic.

A recent study by researchers at the University of Vienna tested leafy vegetables that were grown in Switzerland, Spain, and Italy, and were sold in Swiss supermarkets. The study also tested vegetables harvested directly from Israeli farmlands.

Tire ingredients were found in 11 out of 15 samples gathered from Swiss supermarkets and 9 out of 13 samples collected from Israeli fields. Among these are 6PPD, a tire additive that has been identified as the cause of the extensive deaths of coho salmon on the US West Coast.

The researchers say that farmers may be introducing tire additives by irrigating crops with treated wastewater or by using sewage sludge as fertilizer. Airborne tire particles may also be settling on farm soil.

The concentration of tire particles found in the leafy vegetables are relatively low, but it is troubling that we are eating dangerous chemicals used to improve the quality of tires.

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Leafy Vegetables Found to Contain Tire Additives

Photo, posted October 14, 2014, courtesy of Green Mountain Girls Farm via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Action on the toxic chemical from tires

December 13, 2023 By EarthWise Leave a Comment

Since the 1990s, populations of coho salmon in streams and urban creeks up and down the West Coast have been dying in large numbers. Scientists at the University of Washington began studying the mysterious deaths and it took years to figure out what was going on. They analyzed water samples from urban creeks and found that chemicals from vehicle tires were present. By soaking tires in water, they found that more than 2,000 chemicals were present. It took three years to narrow down the suspect list to one chemical: a toxin called 6PPD-quinone, which is produced when the common tire preservative 6PPD mixes with oxygen. It is that chemical that was responsible for the salmon die-off.

6PPD-quinone is toxic enough to quickly kill some fish. Studies showed that concentrations of the chemical in stormwater were found to be lethal for coho salmon following exposures lasting only a few hours.

Despite the discovery, the tire industry has continued to use the chemical in its products. The industry says 6PPD is an antioxidant and antiozonant that helps prevent degradation and cracking of tires in the environment and is essential for the performance and safety of vehicles.

Last year, California regulators directed the tire industry to seek out substitutes for 6PPD. The U.S. Tire Manufacturers Association pledged to investigate possible safer alternatives to the chemical.

In November, spurred by a petition by West Coast tribes whose lifeways depend on coho salmon, the EPA said it will study the impact of 6PPD with an eye to potentially banning its use.

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After Salmon Deaths, EPA Takes Aim at Toxic Chemical Issuing from Car Tires

Photo, posted May 31, 2021, courtesy of Chris Yarzab via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Upcycling Plastic Waste | Earth Wise

August 23, 2023 By EarthWise Leave a Comment

People have generated 8 billion tons of plastic waste over time and less than 10% of it has been recycled. Millions of tons of it escapes into the oceans. Plastic piles up virtually everywhere on earth.

There are many approaches to dealing with the plastic waste problem and no one of them is a magic bullet. Engineers at Stanford University have investigated the prospects for upcycling plastic waste for use in infrastructure like buildings and roads.

They used a mix of computer modeling, scientific research, experimental and field data to analyze the potential for using plastic waste in infrastructure.

Among their findings is that recycled glass fiber reinforced polymer composite – which is a tensile plastic commonly used in car, boat, and plane parts – is a promising material for reuse in buildings.

Roads in which waste plastic is melted down and mixed with conventional paving materials are becoming more common around the world. India has installed over 60,000 miles of these roads. Studies show that roads containing waste plastic have the potential to perform better than conventional roads. They can last longer, are more durable, can tolerate wide temperature swings, and are more resistant to water damage, cracking, and potholes. Such roads rely less upon virgin fossil resources, which is obviously advantageous.

Upcycling plastic waste in infrastructure is attracting increasing interest because it creates value from something that is strictly a liability and may end up having regulatory advantages as societies move toward more environmentally friendly and sustainable policies.

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Can we use plastic waste to build roads, buildings, and more?

Photo, posted October 7, 2022, courtesy of the Grand Canyon National Park via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio