chemical bonds

Forever chemicals in water

April 23, 2024 By EarthWise Leave a Comment

So-called forever chemicals are pervasive in a wide range of products. These are man-made substances called per- and polyfluoroalkyls or PFAS. They get their unfortunate nickname because the chemical bonds in them are so strong that the compounds don’t break down for hundreds or even thousands of years.

PFAS compounds are used in makeup, dental floss, nonstick pans, food wrappers, pesticides, stain-resistant fabrics and carpets, firefighting foams, and more. High level exposure to some of these chemicals has been linked to a variety of health problems include high cholesterol, liver and immune system damage, pregnancy problems, and kidney and testicular cancer.

A recent study published in the journal Nature Geoscience has found that PFAS chemicals are showing up in water around the world. The study looked at more than 45,000 water samples and found that about 31% of ground water tested that wasn’t even near any obvious source of PFAS contamination had levels of the chemicals that are considered harmful to human health by the EPA. About 16% of surface water samples – streams, rivers, ponds, and lakes – also not near any known source, had similar hazardous PFAS levels.

The EPA has now imposed strict new drinking water limits for six types of PFAS. Going forward, water systems are required to monitor for these chemicals and remove them if they are found above allowable levels. The new rules make the United States one of the strictest countries in the world in terms of regulating PFAS in water.

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EPA puts limits on ‘forever chemicals’ in drinking water

Photo, posted May 5, 2020, courtesy of Brandon Shaw via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Better Way To Recycle Plastics | Earth Wise

November 10, 2022 By EarthWise Leave a Comment

The global accumulation of plastic waste is an ever-growing problem. At least five billion tons of the stuff has accumulated on land and sea and is even showing up in the bodies of animals and humans. Recycling plastic instead of making even more of it seems like an essential thing to do but it has proven to be extremely challenging.

The main problem is that plastics come in many different varieties and the ways of breaking them down into a form that can be reused are very specific to each type of plastic. Sorting plastic waste by plastic type is extremely impractical at large scale. Certainly, most consumers can’t do it themselves. As a result, most plastic gathered in recycling programs ends up in landfills.

New research at MIT has developed a chemical process using a catalyst based on cobalt that is very effective at breaking down a variety of plastics, including polyethylene and polypropylene, which are the two most widely produced plastics. The MIT process breaks plastics down into propane. Propane can be used as a fuel or as a feedstock for making many different products, including new plastics.

Plastics are hard to recycle because their long-chain molecules are very stable and difficult to break apart. Most chemical methods for breaking their chemical bonds produce a random mix of different molecules which would somehow have to be sorted out in order to be useful for anything.

The new process uses a catalyst called a zeolite that contains cobalt nanoparticles. The catalyst selectively breaks down various plastic polymer molecules and turns more than 80% of them into propane.

The researchers are still studying the economics and logistics of the method, but it looks quite promising.

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New process could enable more efficient plastics recycling

Photo, posted April 25, 2016, courtesy of NOAA Coral Reef Ecosystem Program via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Much More Microplastics In The Ocean | Earth Wise

January 28, 2020 By EarthWise Leave a Comment

We’ve been hearing more and more about plastic contamination (microplastics) in the ocean. It is pulled from the nostrils of sea turtles, found in Antarctic waters, and tracked in increasing quantities in sedimentary layers dating back to the 1940s. A new study by researchers from the Scripps Institution of Oceanography suggests that there could be a million times more pieces of plastic in the ocean than previously estimated.

Oceanographers found that some of the tiniest countable microplastic particles in seawater occur at much higher concentrations than previously measured. Apparently, the traditional way of counting marine microplastics most likely misses the smallest particles, and therefore underestimates the number of particles by a factor of anywhere from 10,000 to a million.

The new measurements estimate that the oceans may be contaminated by 8 million pieces of so-called mini-microplastics per cubic meter of water. Earlier studies that only looked at larger pieces of plastic found only 10 pieces per cubic meter.

Microplastic studies typically trawl or pull a fine net behind a ship to collect samples. But the meshes previously used could only capture plastics as small as 333 microns. The new study found plastic particles as small as 10 microns, which is less than the width of a human hair.

Plastics keep breaking down into smaller and smaller particles, but they are so chemically strong that their chemical bonds don’t break down. They remain bits of plastic. Scientists are concerned that these particles can get small enough to enter the human bloodstream. The potential effects on human health are not well known and not extensively studied.

The problem of plastics just keeps getting bigger.

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Microplastics a million times more abundant in the ocean than previously thought

Photo courtesy of UC San Diego.

Earth Wise is a production of WAMC Northeast Public Radio.