caution

Flow batteries are rechargeable batteries in which liquid electrolytes flow through one or more chemical cells from one or more tanks. The electrolytes are redox pairs, that is, chemical compounds that can reversibly undergo reduction and oxidation reactions. The most common redox electrolytes include elements like vanadium, chromium, iron, zinc, and bromine. Flow batteries can provide large amounts of both electrical power and stored energy based on the size of the electrolyte tanks. As a result, they can be scaled up far more readily than other battery technologies.

Flow batteries are safe, stable, long-lasting, and their electrolytes can easily be refilled. They have significant potential for use in utility-scale storage for renewable energy systems.

Researchers at Northwestern University have developed a redox flow battery based on an organic industrial-scale waste product. The material – triphenylphosphine oxide or TPPO – is produced in the thousands of tons each year. It is byproduct of producing a variety of substances including some vitamins, pharmaceuticals, agrochemicals, and other bulk chemicals. For the most part, TPPO is of little use and must be carefully discarded.

The current market for redox flow batteries is very small but is expected to grow over time as the need for utility-scale energy storage continues to expand. A battery technology based on a waste material that is already produced in high volume and that must otherwise be disposed of with caution would have significant advantages.

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Green battery discovery turns trash into treasure

Photo, posted January 12, 2015, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Researchers are considering a wide range of approaches to mitigate the effects of global climate change. Among these are various strategies of geoengineering, which must be viewed with enormous caution, given the high likelihood of unintended consequences from almost anything we might do.

Researchers at the International Institute for Applied Systems Analysis have investigated potential strategies for cooling the planet in the absence of Arctic sea ice.

The Arctic region is heating up faster than any other place on earth and its sea ice is rapidly disappearing. Estimates are that summer sea ice in the Arctic Ocean will be largely gone within a generation. Arctic ice and snow reflect the sun’s energy into space, which helps to keep the planet cool. What happens if that ice is gone?

The researchers explored the fact that the Arctic Ocean ice actually insulates the Arctic atmosphere from the warmer water under the ice. Without the ice layer, the surface water would actually increase air temperatures by 20 degrees C during the winter. That in turn would increase the heat irradiated into space and thereby cool down the planet.

The Arctic sea ice is in part maintained because the upper regions of the Arctic Ocean have lower salinity than the Atlantic Ocean. This stops Atlantic water from flowing above the cold Arctic waters. So, if we were to somehow deliberately increase the salinity of the Arctic Ocean surface water, warmer, less salty Atlantic Ocean water would flow in, increase the temperature of the Arctic atmosphere, and release heat trapped in the ocean into space.

It all sounds pretty crazy, but the researchers say that given the seriousness of climate change, all options should be considered when dealing with it.

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Could we cool the Earth with an ice-free Arctic?

Photo, posted August 19, 2016, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A green battery from industrial waste

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Cooling The Earth With A Warmer Arctic | Climate Change | Earth Wise

Researchers are considering a wide range of approaches to mitigate the effects of global climate change. Among these are various strategies of geoengineering, which must be viewed with enormous caution, given the high likelihood of unintended consequences from almost anything we might do.

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