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Liquid Fuel From Sunshine | Earth Wise

July 6, 2023 By EarthWise Leave a Comment

Producing liquid fuel from sunshine

A key goal of artificial photosynthesis research is to be able to produce a useful liquid fuel using only carbon dioxide, water, and sunlight in a single step.  Such a so-called solar fuel would produce net zero carbon emissions and would be completely renewable.

Bioethanol has long been touted as a green alternative to fossil fuels, since it is made from plants rather than petroleum.  But producing it takes up agricultural land that could be used to grow food instead and there are emissions associated with many aspects of the process by which plant mass becomes fuel.

Researchers from the University of Cambridge in the UK have developed a so-called artificial leaf that produces ethanol or propanol – usable liquid fuels – in a single step.  They developed a copper and palladium-based catalyst that allows the artificial leaf to directly produce multicarbon complex chemicals.  Earlier versions of artificial leaves could make simple chemicals, such as syngas, which would then require additional processing to turn into high-density fuels.

The new device produces liquid fuel from carbon dioxide and water simply by shining sunlight on it.

At present, the artificial leaf is a proof-of-concept device that exhibits only modest efficiency.  The researchers are working to optimize the device’s light absorbers so that they can better make use of sunlight and to optimize the catalyst so that it can convert more of the sunlight into fuel.  In addition, the device needs to be scaled up so that it can produce large volumes of fuel.

All that being said, it is an important step towards people being able to do what plants have been doing for millions of years.

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Driving on sunshine: clean, usable liquid fuels made from solar power

Photo, posted March 23, 2015, courtesy of Astro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fuel From Lignin | Earth Wise

November 26, 2020 By EarthWise Leave a Comment

Lignin as a fuel

Lignin is an organic polymer that provides the rigid structure of plants and is what gives wood and bark their characteristic properties.  Lignin typically comprises between 20 and 35% of the mass of wood.  The two major substances extracted from trees, grasses, and other biomass materials are cellulose and lignin.  Cellulose is used to make paper, bioethanol, and other products, but lignin is largely unused because it is difficult to break down into useful substances such as feedstocks for fuels.  As a result, lignin is largely wasted.  Worldwide, some 50 million tons of lignin are produced from paper and bioethanol manufacturing each year and almost all of that is simply burned to generate heat.

Lignin can be broken down using pyrolysis techniques at high temperatures to create bio-oils, but those oils lack sufficient hydrogen and contain too much oxygen to be useful as fuels.  There is a process called hydrodeoxygenation that adds hydrogen and removes oxygen, but it requires high temperatures and very high pressures as well as producing char and tar that reduces the efficiency of the process.

Researchers at Georgia Tech recently published work describing a new process for turning lignin into useful products.  They developed a dual catalyst system of super-acid and platinum particles that adds hydrogen and removes oxygen from lignin bio-oil and makes it useful as a fuel and source of chemical feedstocks. 

The new process could help meet the growing demand for bio-based oils as well as helping the forest product, paper, and bioethanol industries by providing an additional revenue stream from what previously was a waste product.

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New Process Boosts Lignin Bio-oil as a Next-Generation Fuel

Photo, posted August 16, 2017, courtesy of evcabartakova via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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